http://www.cnr.it/ontology/cnr/individuo/prodotto/ID313705
Modulation of the electrochemical properties of SBS-based anionic membranes by the amine molecular structure (Articolo in rivista)
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- Modulation of the electrochemical properties of SBS-based anionic membranes by the amine molecular structure (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Alternative label
Filpi, Antonio; Boccia, Massimiliano; Pucci, Andrea; Ciardelli, Francesco (2013)
Modulation of the electrochemical properties of SBS-based anionic membranes by the amine molecular structure
in E-Polymers
(literal)
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- Filpi, Antonio; Boccia, Massimiliano; Pucci, Andrea; Ciardelli, Francesco (literal)
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- University of Pisa; Acta SpA; CNR NANO; INSTM; Spin Pet Srl (literal)
- Titolo
- Modulation of the electrochemical properties of SBS-based anionic membranes by the amine molecular structure (literal)
- Abstract
- In this work, different amines (bifunctional, as diazabicyclo[2.2.2]octane (Dabco) and monofunctional, as N-methylimidazole or trimethylamine) were utilized for the amination of benzyl chloride-grafted polystyrene-b-poly(butadiene)-b-polystyrene triblock copolymers (SBS-g-VBC). The use of Dabco solutions in mixture with variable amounts of monoamine or at different concentration allowed to modulate the degree of crosslinking of the SBS-based membranes and their electrochemical parameters. More specifically, tuning Dabco concentration permitted the reduction of water uptake without significantly affecting ionic conductivity. (literal)
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