http://www.cnr.it/ontology/cnr/individuo/prodotto/ID312486
Advances in 1-dimensional semiconductor nanostructures: from self-assembly to functional nanodevices (Abstract/Comunicazione in atti di convegno)
- Type
- Label
- Advances in 1-dimensional semiconductor nanostructures: from self-assembly to functional nanodevices (Abstract/Comunicazione in atti di convegno) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Alternative label
P. Prete, N. Lovergine (2012)
Advances in 1-dimensional semiconductor nanostructures: from self-assembly to functional nanodevices
in International Conference on Nanomaterials: Fundamentals and Applications, Strbské Pleso, High Tatras, Slovak republic, October, 3-6 2012
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- P. Prete, N. Lovergine (literal)
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- The 1st International Conference on Nanomaterials: Fundamentals and Applications- Book of Abstract (literal)
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- CNR-IMM, UOS Lecce, Italy
University of Salento, Lecce, Italy (literal)
- Titolo
- Advances in 1-dimensional semiconductor nanostructures: from self-assembly to functional nanodevices (literal)
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- Andrea Fedorková (literal)
- Abstract
- Recently, free-standing nanowires (NWs) based on III-V compound semiconductors have attracted much interest due to their unique physical properties and huge potential for future realization of nanodevices with innovative and/or enhanced functionalities: these systems are indeed, being considered as ideal building blocks for the fabrication of novel and efficient nanophotonic and nano-electronic devices, and III-generation photovoltaic cells. High-quality III-V NW-based heterostructures, with sharp interfaces and good control in size, shape and material composition, can nowadays be grown using various techniques, including metalorganic vapor phase epitaxy (MOVPE. Self-assembly of III-V NWs by MOVPE through the Au-catalyst assisted (so-called Vapour-Liquid-Solid, VLS) mechanism is a most promising technology for the synthesis of NW-based devices, but it still requires demonstrating its entire potentials in terms of materials/device performances and industrial scalability.
The growth of device-quality NW structures and the study of their physical properties is crucial in order to improve/optimize the performances of NW-based devices.
In this lecture, the self-assembly by MOVPE and the properties of GaAs NWs and core-shell GaAs-AlGaAs NWs will be reported as a case study. The controlled growth of vertically well-aligned GaAs, AlGaAs and GaAs-AlGaAs core-shell NWs will be presented, focusing on both NW properties (morphology, size, growth rate, inner composition, defects content, and luminescence) and on their dependence on MOVPE self-assembly conditions.
Moreover, the fabrication of novel single-NW photo-detectors based on MOVPE-grown GaAs and GaAs-AlGaAs core-shell nanostructures will be reported, along with their spectral photocurrent properties. Core-shell structures are advantageous in this respect, as they reduce substantially carrier recombination at the NW surface, thus achieving higher quantum efficiency. Moreover, the GaAs/AlGaAs heterostructure offers other benefits such as an almost strain-free NW system due to the close lattice matching between core and shell materials, and possibility of band bending at the hetero-interface which confines the electrons and facilitates their transport.
The potentials of self-assembly MOVPE technology for photovoltaic applications through the growth of large and dense arrays of well-aligned GaAs and GaAs-AlGaAs NWs on Si substrates will be finally presented and discussed. (literal)
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