Synthesis of Heterodimetallic Complexes by Reaction of a Terminal Phosphido Pt Complex with Metal-Based Nucleophiles and Electrophiles (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Synthesis of Heterodimetallic Complexes by Reaction of a Terminal Phosphido Pt Complex with Metal-Based Nucleophiles and Electrophiles (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/ejic.201301188 (literal)

Alternative label

• Latronico, Mario; Todisco, Stefano; Gallo, Vito; Englert, Ulli; Mastrorilli, Piero (2014)
  Synthesis of Heterodimetallic Complexes by Reaction of a Terminal Phosphido Pt Complex with Metal-Based Nucleophiles and Electrophiles
  in European journal of inorganic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Latronico, Mario; Todisco, Stefano; Gallo, Vito; Englert, Ulli; Mastrorilli, Piero (literal)

Pagina inizio

• 1669 (literal)

Pagina fine

• 1678 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 2014 (literal)

Rivista

• European journal of inorganic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 10 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 10 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Politecn Bari; Ist CNR Chim Composti Organometall ICCOM; RWTH Aachen University (literal)

Titolo

• Synthesis of Heterodimetallic Complexes by Reaction of a Terminal Phosphido Pt Complex with Metal-Based Nucleophiles and Electrophiles (literal)

Abstract

• The complex trans-[PtCl(PCy2)(PHCy2)(2)] (1) possesses a terminal phosphanido group (PCy2) and a chloride ligand, which render it a good candidate for the synthesis of phosphanido-bridged heterodimetallic species (PHCy2)(2)Pt(-PCy2)M-L by reaction either with carbonyl metalates, as metal-based nucleophiles, or with metal-based electrophiles. The heterodinuclear complexes [(PHCy2)(2)Pt(-PCy2)Co(CO)(3)](Pt-Co) (2), [(PHCy2)(2)Pt(-PCy2)Mo(CO)(2)Cp](Pt-Mo) (3), and [(PHCy2)(2)Pt(-PCy2)W(CO)(2)Cp](Pt-W) (4) are obtained by reaction of 1 with the carbonyl metalates Na[Co(CO)(4)], Na[Mo(CO)(3)Cp] and Na[W(CO)(3)Cp], respectively. Although 2 is reluctant to react with carbon monoxide, 3 and 4 are promptly carbonylated under ambient conditions to afford mixtures of the cis and trans isomers of [(PHCy2)(CO)Pt(-PCy2)M(CO)(2)Cp] (M = Mo or W), which interconvert through dissociation/reassociation of the CO ligand coordinated to the Pt centre. The reaction of 1 with AuCl(PPh3) leads to the formation of the trinuclear Pt2Au complexes cis- and trans-[{Cl(PHCy2)(2)Pt(-PCy2)}(2)Au]Cl (cis- and trans-[8]Cl), in which a Au atom bridges two molecules of 1 through the originally terminal phosphanide ligands. (literal)

Prodotto di

• Nuovi materiali per 'storage' e produzione di idrogeno (PM.P03.005.001) (Modulo)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• PIETRO MASTRORILLI (Unità di personale esterno)

Insieme di parole chiave

• Parole chiave di "Synthesis of Heterodimetallic Complexes by Reaction of a Terminal Phosphido Pt Complex with Metal-Based Nucleophiles and Electrophiles" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Nuovi materiali per 'storage' e produzione di idrogeno (PM.P03.005.001) (Modulo)

Autore CNR di

• PIETRO MASTRORILLI (Unità di personale esterno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• European journal of inorganic chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "Synthesis of Heterodimetallic Complexes by Reaction of a Terminal Phosphido Pt Complex with Metal-Based Nucleophiles and Electrophiles" (Insieme di parole chiave)