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Dissociative electron attachment to vibrationally excited H2 molecules involving the 2Sigma+g resonant Rydberg electronic state (Articolo in rivista)
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- Label
- Dissociative electron attachment to vibrationally excited H2 molecules involving the 2Sigma+g resonant Rydberg electronic state (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.chemphys.2011.05.004 (literal)
- Alternative label
Celiberto, Roberto; Janev, Ratko K.; Wadehra, J. M.; Tennyson, Jonathan L. (2012)
Dissociative electron attachment to vibrationally excited H2 molecules involving the 2Sigma+g resonant Rydberg electronic state
in Chemical physics (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Celiberto, Roberto; Janev, Ratko K.; Wadehra, J. M.; Tennyson, Jonathan L. (literal)
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- http://www.scopus.com/record/display.url?eid=2-s2.0-84860884744&origin=inward (literal)
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- Politecnico di Bari; Consiglio Nazionale delle Ricerche; Macedonian Academy of Sciences and Arts; Forschungszentrum Jülich (FZJ); Wayne State University; UCL (literal)
- Titolo
- Dissociative electron attachment to vibrationally excited H2 molecules involving the 2Sigma+g resonant Rydberg electronic state (literal)
- Abstract
- Dissociative electron attachment cross sections (DEA) on vibrationally excited H2 molecule taking place via the 2Sigma+g Rydberg-excited resonant state are studied using the local complex potential (LCP) model for resonant collisions. The cross sections are calculated for all initial vibrational levels (vi = 0-14) of the neutral molecule. In contrast to the previously noted dramatic increase in the DEA cross sections with increasing vi, when the process proceeds via the X 2Sigma+u shape resonance of H2, for the 2Sigma+g Rydberg resonance the cross sections increase only gradually up to vi = 3 and then decrease. Moreover, the cross sections for vi >= 6 exhibit pronounced oscillatory structures. A discussion of the origin of the observed behavior of calculated cross sections is given. The DEA rate coefficients for all vi levels are also calculated
in the 0.5-1000 eV temperature range. (literal)
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