New strategies to improve Eu light emission in Si-based matrices (Contributo in atti di convegno)

Type
Label
  • New strategies to improve Eu light emission in Si-based matrices (Contributo in atti di convegno) (literal)
Anno
  • 2014-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1117/12.2052151 (literal)
Alternative label
  • G. Franzò, G. Bellocchi, S. Boninelli, M. Miritello and F. Iacona (2014)
    New strategies to improve Eu light emission in Si-based matrices
    in 4th Conference on Silicon Photonics and Photonic Integrated Circuits, Brussels, BELGIUM, APR 14-17, 2014
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • G. Franzò, G. Bellocchi, S. Boninelli, M. Miritello and F. Iacona (literal)
Pagina inizio
  • 913307 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 9133 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 8 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • MATIS IMM CNR, via Santa Sofia 64, 95121 Catania, Italy; Dipartimento di Fisica e Astronomia, Università di Catania, via Santa Sofia 64, 95121 Catania, Italy (literal)
Titolo
  • New strategies to improve Eu light emission in Si-based matrices (literal)
Abstract
  • A promising approach to obtain light emission from Si-based materials is represented by doping with rare earths and in particular with Eu. In this paper the comparison of the performances of SiO2 and SiOC layers as host matrices for optically active Eu ions is presented. A SiO2 matrix allows to observe light emission from both Eu2+ and Eu3+ ions, owing to a proper tuning of the thermal annealing process used to optically activate the rare earth. However the photoluminescence efficiency of both ions remains relatively low and quite far from the requirements for technological applications, mainly due to the extensive formation of Eu-containing precipitates. A detailed study of the structural and optical properties of these layers allowed us to analyze and elucidate the clustering process and to find suitable strategies to minimize it. We found that the substitution of the SiO2 matrix with a SiOC film allows to obtain a very bright light emission at about 440 nm from Eu2+ ions. In fact SiOC is able to efficiently promote the Eu reduction; furthermore, Eu ions are characterized by an enhanced mobility and solubility in this matrix and, as a consequence, Eu precipitation is strongly reduced Finally, by taking advantage of the dependence of the photoluminescence peak position on the Eu concentration, an intense white emission is obtained at room temperature by combining two layers with different Eu contents. Since SiOC is a material fully compatible with standard Si technology, Eu-doped SiOC layers can be considered a highly interesting candidate for applications in photonics or in solid-state lighting. (literal)
Editore
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Autore CNR di
Prodotto
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Editore di
Insieme di parole chiave di
data.CNR.it