Characterisation of the electronic structure of some stable nitroxyl radicals using variable energy photoelectron spectroscopy (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Characterisation of the electronic structure of some stable nitroxyl radicals using variable energy photoelectron spectroscopy (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/c4cp00867g (literal)

Alternative label

• Kovac B.; Ljubic I.; Kivimaki A.; Coreno M.; Novak I. (2014)
  Characterisation of the electronic structure of some stable nitroxyl radicals using variable energy photoelectron spectroscopy
  in PCCP. Physical chemistry chemical physics (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Kovac B.; Ljubic I.; Kivimaki A.; Coreno M.; Novak I. (literal)

Pagina inizio

• 10734 (literal)

Pagina fine

• 10742 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.scopus.com/inward/record.url?eid=2-s2.0-84900821181&partnerID=q2rCbXpz (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 16 (literal)

Rivista

• PCCP. Physical chemistry chemical physics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 22 (literal)

Note

• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Ruder Boskovic Institute, Bijenicka cesta 54, HR-10000 Zagreb, Croatia; CNR-IOM, Laboratorio Nazionale TASC, 34149 Trieste, Italy; CNR-IMIP Montelibretti, 00016 Rome, Italy; Charles Sturt University, POB 883, Orange, NSW 2800, Australia (literal)

Titolo

• Characterisation of the electronic structure of some stable nitroxyl radicals using variable energy photoelectron spectroscopy (literal)

Abstract

• The photoionization of three stable nitroxyl radicals has been studied in the valence and core regions using synchrotron radiation. We observed different variations of the relative band intensities with the photon energy for two pyrrolidine nitroxyls (nitroxyl8 and nitroxyl9) in the valence ionization region. This is due to strong intramolecular interactions between the amide substituent and the ring ?-orbital when present. In the core ionization region we observed chemical shifts which were consistent with the relative electron affinities of different atoms. We also observed the multiplet splitting of core level binding energies in the final ionic states. The core electron binding energies calculated via the restricted open shell Hartree-Fock based ?SCF method exhibit good agreement with the experimental core ionization bands and with the assignment of the spectra by empirical analysis. This journal is © the Partner Organisations 2014. (literal)

Prodotto di

• Sistemi a bassa densita' e nanostrutture (MD.P06.016.002) (Modulo)
• Institute of structure of matter (ISM) (Istituto)
• DINAMICA DEI PROCESSI ATOMICI E MOLECOLARI (MD.P03.026.004) (Modulo)

Autore CNR

• MARCELLO CORENO (Unità di personale interno)
• ANTTI EERIK KIVIMAKI (Persona)

Incoming links:

Autore CNR di

• MARCELLO CORENO (Unità di personale interno)
• ANTTI EERIK KIVIMAKI (Persona)

Prodotto

• Institute of structure of matter (ISM) (Istituto)
• DINAMICA DEI PROCESSI ATOMICI E MOLECOLARI (MD.P03.026.004) (Modulo)
• Sistemi a bassa densita' e nanostrutture (MD.P06.016.002) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• PCCP. Physical chemistry chemical physics (Rivista)