Enhanced hydrogen production by photoreforming of renewable oxygenates through nanostructured Fe2O3 polymorphs (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Enhanced hydrogen production by photoreforming of renewable oxygenates through nanostructured Fe2O3 polymorphs (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/adfm.201302043 (literal)

Alternative label

• Carraro G.; MacCato C.; Gasparotto A.; Montini T.; Turner S.; Lebedev O.I.; Gombac V.; Adami G.; Van Tendeloo G.; Barreca D.; Fornasiero P. (2014)
  Enhanced hydrogen production by photoreforming of renewable oxygenates through nanostructured Fe2O3 polymorphs
  in Advanced functional materials (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Carraro G.; MacCato C.; Gasparotto A.; Montini T.; Turner S.; Lebedev O.I.; Gombac V.; Adami G.; Van Tendeloo G.; Barreca D.; Fornasiero P. (literal)

Pagina inizio

• 372 (literal)

Pagina fine

• 378 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Autori stranieri; highly cited paper (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://onlinelibrary.wiley.com/doi/10.1002/adfm.201302043/abstract (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 24 (literal)

Rivista

• Advanced functional materials (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 3 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1-3 : Department of Chemistry, University of Padova, INSTM, via F. Marzolo 1, 35131 Padova, Italy / 4,7,11 : Department of Chemical and Pharmaceutical Sciences, ICCOM-CNR Trieste Research Unit, University of Trieste, via L. Giorgieri 1, 34127 Trieste, Italy / 5,9 : EMAT, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerpen, Belgium / 6 : Laboratoire CRISMAT, UMR 6508, CNRS-ENSICAEN, Bd. Maréchal Juin 6, 14050 Caen CEDEX 4, France / 8 : Department of Chemical and Pharmaceutical Sciences, University of Trieste, Via L. Giorgieri 1, 34127 Trieste, Italy / 10 : CNR-IENI and INSTM, Department of Chemistry, University of Padova, via F. Marzolo 1, 35131 Padova, Italy (literal)

Titolo

• Enhanced hydrogen production by photoreforming of renewable oxygenates through nanostructured Fe2O3 polymorphs (literal)

Abstract

• Sunlight-driven hydrogen production via photoreforming of aqueous solutions containing renewable compounds is an attractive option for sustainable energy generation with reduced carbon footprint. Nevertheless, the absence of photocatalysts combining high efficiency and stability upon solar light activation has up to date strongly hindered the development of this technology. Herein, two scarcely investigated iron(III) oxide polymorphs, ?- and ?-Fe2O3, possessing a remarkable activity in sunlight-activated H2 generation from aqueous solutions of renewable oxygenates (i.e., ethanol, glycerol, glucose) are reported. For ?-Fe 2O3 and ?-Fe2O3, H2 production rates up to 225 and 125 mmol h-1 m-2 are obtained, with significantly superior performances with respect to the commonly investigated ?-Fe2O3. Sunlight-activated photoreforming of renewable oxygenates promoted by Fe2O3 nanosystems is a very attractive process for hydrogen production. In this context, scarcely investigated ?- and ?-Fe2O3 polymorphs, fabricated by chemical vapor deposition, show very promising performances for photocatalytic solar hydrogen generation. The present approach holds a remarkable potential even for the synthesis of added-value by-products, paving the way to manifold technological applications. (literal)

Prodotto di

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Modeling computazionale di sistemi complessi costituiti da molecole interagenti con superfici e nanosistemi (PM.P05.007.002) (Modulo)

Autore CNR

• paolo Fornasiero (Unità di personale esterno)
• DAVIDE BARRECA (Persona)

Insieme di parole chiave

• Parole chiave di "Enhanced hydrogen production by photoreforming of renewable oxygenates through nanostructured Fe2O3 polymorphs" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Modeling computazionale di sistemi complessi costituiti da molecole interagenti con superfici e nanosistemi (PM.P05.007.002) (Modulo)

Autore CNR di

• DAVIDE BARRECA (Persona)
• paolo Fornasiero (Unità di personale esterno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Advanced functional materials (Rivista)

Insieme di parole chiave di

• Parole chiave di "Enhanced hydrogen production by photoreforming of renewable oxygenates through nanostructured Fe2O3 polymorphs" (Insieme di parole chiave)