Natural fluctuation of the sulfur species in volcanic fumaroles. (Articolo in rivista)

Type
Label
  • Natural fluctuation of the sulfur species in volcanic fumaroles. (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Alternative label
  • Montegrossi G.(1); Tassi F.(2); Minissale A.(1); Vaselli O.(2); Buccianti A.(2) (2008)
    Natural fluctuation of the sulfur species in volcanic fumaroles.
    in Journal of non-equilibrium thermodynamics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Montegrossi G.(1); Tassi F.(2); Minissale A.(1); Vaselli O.(2); Buccianti A.(2) (literal)
Pagina inizio
  • 75 (literal)
Pagina fine
  • 102 (literal)
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  • 33 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1 - CNR Ist. Geoscienze Georisorse Sez. Firenze 2 - Dip.to Scienze della Terra UNI-FI (literal)
Titolo
  • Natural fluctuation of the sulfur species in volcanic fumaroles. (literal)
Abstract
  • We describe and discuss the origin of short-term (hours) variations in the concentration of sulfur species (SO2, H2S, and S-8(0)) of crater fumaroles discharging at different temperatures (up to 410 degrees C) from five volcanic systems. Sulfur species can be investigated as an independent subsystem within the whole composition characterizing the fumarolic fluids, their chemical behavior being governed by similar laws in volcanic systems. The measured data are time dependent and show regular oscillations whose amplitude is by far larger than the analytical error. The agreement between the theoretical and the measured concentrations of SO2, H2S, and S-8(0) suggests that the formation of dissipative structures can explain the observed oscillations. Accordingly, the periodicity and the amplitude of the compositional oscillations were found to be in strong relation with the entropy excess of the non-equilibrium systems under investigation. The results of our study suggest that the amplitude and magnitude of short-term natural (self-induced) fluctuations of the sulfur species caused by the presence of the dissipative structures, and their comparison with the compositional variations of other subsystems, should be taken into serious account for geochemical monitoring purposes. (literal)
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