http://www.cnr.it/ontology/cnr/individuo/prodotto/ID295500
Au@Ag Core-Shell Nanocubes: Epitaxial Growth Synthesis and Surface-Enhanced Raman Scattering Performance (Articolo in rivista)
- Type
- Label
- Au@Ag Core-Shell Nanocubes: Epitaxial Growth Synthesis and Surface-Enhanced Raman Scattering Performance (Articolo in rivista) (literal)
- Anno
- 2015-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1039/C4CP05642F (literal)
- Alternative label
Yanting Liu, Jun Zhou, Binbing Wang, Tao Jiang, H.P. Ho, Lucia Petti and Pasquale Mormile (2015)
Au@Ag Core-Shell Nanocubes: Epitaxial Growth Synthesis and Surface-Enhanced Raman Scattering Performance
in Physical Chemistry Chemical Physics
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Yanting Liu, Jun Zhou, Binbing Wang, Tao Jiang, H.P. Ho, Lucia Petti and Pasquale Mormile (literal)
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Titolo
- Au@Ag Core-Shell Nanocubes: Epitaxial Growth Synthesis and Surface-Enhanced Raman Scattering Performance (literal)
- Abstract
- Novel Au@Ag core-shell nanocubes (NCs) were successfully prepared by the controlled epitaxial growth of Ag shells onto Au nanoellipsoids (NEs) in the presence of surfactants. The growth mechanism of the Au@Ag core-shell NCs was systematically investigated by analyzing their morphology, optical properties, and crystallography. The localized surface plasmon resonance (LSPR) characteristics and the electric field distribution of the Au@Ag core-shell NCs were studied using the finite element method (FEM) based on the plasmon hybridization theory. Compared with pure Ag NCs, the absorption spectrum of the Au@Ag core-shell NCs exhibits a red shift and a weak shoulder near 550 nm, and the notable enhancement of electric field occurs around the corners along the long-axis of Au ellipsoidal core because of plasmonic resonant coupling. Surface-enhanced Raman scattering (SERS) of the Au@Ag core-shell NCs labeled with 4-mercaptobenzoic acid molecules reveals that the bimetallic core-shell NCs possess efficient SERS activity with an enhancement factor EF = 2.27×106, thus confirming the possibility of using the Au@Ag core-shell NCs as stable probe for SERS-based biosensing applications. (literal)
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