Au@Ag Core-Shell Nanocubes: Epitaxial Growth Synthesis and Surface-Enhanced Raman Scattering Performance (Articolo in rivista)

Type
Label
  • Au@Ag Core-Shell Nanocubes: Epitaxial Growth Synthesis and Surface-Enhanced Raman Scattering Performance (Articolo in rivista) (literal)
Anno
  • 2015-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/C4CP05642F (literal)
Alternative label
  • Yanting Liu, Jun Zhou, Binbing Wang, Tao Jiang, H.P. Ho, Lucia Petti and Pasquale Mormile (2015)
    Au@Ag Core-Shell Nanocubes: Epitaxial Growth Synthesis and Surface-Enhanced Raman Scattering Performance
    in Physical Chemistry Chemical Physics
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Yanting Liu, Jun Zhou, Binbing Wang, Tao Jiang, H.P. Ho, Lucia Petti and Pasquale Mormile (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICIB-CNR (literal)
Titolo
  • Au@Ag Core-Shell Nanocubes: Epitaxial Growth Synthesis and Surface-Enhanced Raman Scattering Performance (literal)
Abstract
  • Novel Au@Ag core-shell nanocubes (NCs) were successfully prepared by the controlled epitaxial growth of Ag shells onto Au nanoellipsoids (NEs) in the presence of surfactants. The growth mechanism of the Au@Ag core-shell NCs was systematically investigated by analyzing their morphology, optical properties, and crystallography. The localized surface plasmon resonance (LSPR) characteristics and the electric field distribution of the Au@Ag core-shell NCs were studied using the finite element method (FEM) based on the plasmon hybridization theory. Compared with pure Ag NCs, the absorption spectrum of the Au@Ag core-shell NCs exhibits a red shift and a weak shoulder near 550 nm, and the notable enhancement of electric field occurs around the corners along the long-axis of Au ellipsoidal core because of plasmonic resonant coupling. Surface-enhanced Raman scattering (SERS) of the Au@Ag core-shell NCs labeled with 4-mercaptobenzoic acid molecules reveals that the bimetallic core-shell NCs possess efficient SERS activity with an enhancement factor EF = 2.27×106, thus confirming the possibility of using the Au@Ag core-shell NCs as stable probe for SERS-based biosensing applications. (literal)
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