Catalytic partial oxidation of methane over nanosized Rh supported on Fecralloy foams (Articolo in rivista)

Type
Label
  • Catalytic partial oxidation of methane over nanosized Rh supported on Fecralloy foams (Articolo in rivista) (literal)
Anno
  • 2014-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.ijhydene.2014.05.076 (literal)
Alternative label
  • Verlato, E, Barison, S., Cimino, S., Dergal, F., Lisi, L., Mancino, G., Musiani, M., Vázquez-Gómez, L. (2014)
    Catalytic partial oxidation of methane over nanosized Rh supported on Fecralloy foams
    in International journal of hydrogen energy
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Verlato, E, Barison, S., Cimino, S., Dergal, F., Lisi, L., Mancino, G., Musiani, M., Vázquez-Gómez, L. (literal)
Pagina inizio
  • 11473 (literal)
Pagina fine
  • 11485 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.scopus.com/record/display.url?eid=2-s2.0-84904071489&origin=inward (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 39 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 22 (literal)
Note
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto per l'Energetica e le Interfasi IENI, CNR, Corso Stati Uniti 4, 35127 Padova, Italy / Istituto di Ricerche sulla Combustione IRC, CNR, P.le V. Tecchio 80, 80125 Napoli, Italy / Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques, (C.R.A.P.C.), BP 248, Alger RP 16004 Alger, Algeria (literal)
Titolo
  • Catalytic partial oxidation of methane over nanosized Rh supported on Fecralloy foams (literal)
Abstract
  • Structured catalysts for the partial oxidation of methane were prepared by supporting Rh nanoparticles onto Fecralloy foams at relatively low precious metal loadings. The investigation was focused mainly on an innovative and straightforward preparation procedure consisting in the direct cathodic electrodeposition of Rh onto foam samples. For the sake of comparison, other Rh-based catalysts were prepared with a more traditional approach, by using the same foams and an AlPO4 washcoat layer. The catalysts were characterized by SEM-EDS, XRD and cyclic voltammetry, to assess the Rh surface area, and tested in the CPO of methane to syngas under self-sustained high temperature conditions at short-contact-time. During prolonged CPO tests the performance of electrochemically prepared catalysts underwent a progressive decline, as compared to stable operation of AlPO4 washcoated catalysts, which was mainly ascribed to sintering of Rh nanoparticles, negatively affecting the activity for methane steam reforming. (literal)
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Autore CNR di
Prodotto
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Insieme di parole chiave di
data.CNR.it