Stabilization of N,N '-bis(3-methylphenyl)-N,N '-bis(phenyl)benzidine thin film morphology with UV light (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Stabilization of N,N '-bis(3-methylphenyl)-N,N '-bis(phenyl)benzidine thin film morphology with UV light (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.tsf.2014.03.081 (literal)

Alternative label

• Tomovic, A. Z.; Markesevic, N.; Scarpellini, M.; Bovio, S.; Lucenti, E.; Milani, P.; Zikic, R.; Jovanovic, V. P.; Srdanov, V. I. (2014)
  Stabilization of N,N '-bis(3-methylphenyl)-N,N '-bis(phenyl)benzidine thin film morphology with UV light
  in Thin solid films (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Tomovic, A. Z.; Markesevic, N.; Scarpellini, M.; Bovio, S.; Lucenti, E.; Milani, P.; Zikic, R.; Jovanovic, V. P.; Srdanov, V. I. (literal)

Pagina inizio

• 99 (literal)

Pagina fine

• 103 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0040609014003733 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 562 (literal)

Rivista

• Thin solid films (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 5 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 562 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• University of Belgrade; University of Milan; Consiglio Nazionale delle Ricerche (CNR) (literal)

Titolo

• Stabilization of N,N '-bis(3-methylphenyl)-N,N '-bis(phenyl)benzidine thin film morphology with UV light (literal)

Abstract

• Owing to their low glass transition temperature, T-g, amorphous thin films of N,N'-bis(3-methylphenyl)-N,N'bis(phenyl)benzidine (TPD) undergo morphological changes even at room temperature. It has been noticed previously that exposure to UV light can increase apparent T-g of TPD films and thus stabilize their morphology. However, the reason behind increase in structural stability was not examined at the time. Here we present evidence that TPD molecules undergo photo-oxidation in air when exposed to lambda approximate to 350 nm radiation and that less than 5% of the photo-oxidized species are needed to prevent dewetting of thin TPD films. We propose that photo-oxidized TPD species bind strongly to both ordinary TPD molecules and to terminal hydroxyl groups at the substrate surface, which decreases mobility of TPD molecules and makes thin TPD film less prone to morphology changes. (C) 2014 Elsevier B.V. All rights reserved. (literal)

Prodotto di

• Sintesi e caratterizzazione di molecole organiche e complessi metallorganici con specifiche proprietà ottiche (PM.P04.012.002) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• ELENA LUCENTI (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Stabilization of N,N '-bis(3-methylphenyl)-N,N '-bis(phenyl)benzidine thin film morphology with UV light" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Sintesi e caratterizzazione di molecole organiche e complessi metallorganici con specifiche proprietà ottiche (PM.P04.012.002) (Modulo)

Autore CNR di

• ELENA LUCENTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Thin solid films (Rivista)

Insieme di parole chiave di

• Keywords of "Stabilization of N,N '-bis(3-methylphenyl)-N,N '-bis(phenyl)benzidine thin film morphology with UV light" (Insieme di parole chiave)