Thin Deposits and Patterning of Room-Temperature-Switchable One-Dimensional Spin-Crossover Compounds (Articolo in rivista)

Type
Label
  • Thin Deposits and Patterning of Room-Temperature-Switchable One-Dimensional Spin-Crossover Compounds (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/la104901m (literal)
Alternative label
  • Cavallini, Massimiliano; Bergenti, Ilaria; Milita, Silvia; Kengne, Jean Crispin; Gentili, Denis; Ruani, Giampiero; Salitros, Ivan; Meded, Velimir; Ruben, Mario (2011)
    Thin Deposits and Patterning of Room-Temperature-Switchable One-Dimensional Spin-Crossover Compounds
    in Langmuir
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Cavallini, Massimiliano; Bergenti, Ilaria; Milita, Silvia; Kengne, Jean Crispin; Gentili, Denis; Ruani, Giampiero; Salitros, Ivan; Meded, Velimir; Ruben, Mario (literal)
Pagina inizio
  • 4076 (literal)
Pagina fine
  • 4081 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 27 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 6 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 7 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Consiglio Nazionale delle Ricerche (CNR); Consiglio Nazionale delle Ricerche (CNR); Karlsruhe Institute of Technology (literal)
Titolo
  • Thin Deposits and Patterning of Room-Temperature-Switchable One-Dimensional Spin-Crossover Compounds (literal)
Abstract
  • We present a study on thin deposits and patterning of 1-D spin-crossover compounds Fe-II-(L)(2)H](ClO4)(3)center dot MeOH [L = 4'-(4'''-pyridyl)-1,2':6'1 ''-bis-(pyrazolyl) pyridine] (1) that exhibit a reversible, thermally driven spin transition at room temperature. Micrometric rodlike crystals of 1 on silicon surfaces are achieved by drop casting and solvent annealing. We observed that the crystallinity of thin deposits and spin-transition properties critically depends on the deposition procedure. Furthermore, we proved processability and patterning using unconventional wet lithography that reduces the crystallite formation time by 1 order of magnitude. Thin deposits of 1 were characterized by atomic force microscopy, polarized optical microscopy and X-rays, and the switching properties were characterized by Raman spectroscopy. (literal)
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