Pyridine-CF4: A Molecule with a Rotating Cap (Articolo in rivista)

Type
Label
  • Pyridine-CF4: A Molecule with a Rotating Cap (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp409173v (literal)
Alternative label
  • Maris, Assimo; Favero, Laura B.; Velino, Biagio; Caminati, Walther (2013)
    Pyridine-CF4: A Molecule with a Rotating Cap
    in The journal of physical chemistry. A; American Chemical Society, Washington (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Maris, Assimo; Favero, Laura B.; Velino, Biagio; Caminati, Walther (literal)
Pagina inizio
  • 11289 (literal)
Pagina fine
  • 11292 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 117 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 44 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • University of Bologna, ISMN-CNR, University of Bologna, University of Bologna (literal)
Titolo
  • Pyridine-CF4: A Molecule with a Rotating Cap (literal)
Abstract
  • The rotational spectrum of pyridine-CF4 has been investigated by molecular beam Fourier transform microwave spectroscopy in a supersonic expansion. The CF4 moiety is located as a cap over the pyridine nitrogen, and the two parts are freely rotating with respect to each other. For this reason, in a first approximation, in the m = 0 state only the pyridine ring is rotating along the a-axis, and the value of rotational constant A' is nearly the same of the constant A of isolated pyridine. The (NCCF4)-C-..., distance is 3.372(1) angstrom. The dissociation energy has been estimated, from the centrifugal distortion, to be ca. 10 kJ/mol. (literal)
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