Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells (Articolo in rivista)

Type
Label
  • Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells (Articolo in rivista) (literal)
Anno
  • 2014-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/cssc.201402316 (literal)
Alternative label
  • Bellini, Marco; Bevilacqua, Manuela; Filippi, Jonathan; Lavacchi, Alessandro; Marchionni, Andrea; Miller, Hamish A.; Oberhauser, Werner; Vizza, Francesco; Annen, Samuel P.; Gruetzmacher, H. (2014)
    Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells
    in ChemSusChem (Weinh., Print); J. Wiley & sons, New York (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bellini, Marco; Bevilacqua, Manuela; Filippi, Jonathan; Lavacchi, Alessandro; Marchionni, Andrea; Miller, Hamish A.; Oberhauser, Werner; Vizza, Francesco; Annen, Samuel P.; Gruetzmacher, H. (literal)
Pagina inizio
  • 2432 (literal)
Pagina fine
  • 2435 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 7 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 9 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Consiglio Nazionale delle Ricerche (CNR); Swiss Federal Institute of Technology Zurich; Sun Yat Sen University (literal)
Titolo
  • Energy and Chemicals from the Selective Electrooxidation of Renewable Diols by Organometallic Fuel Cells (literal)
Abstract
  • Organometallic fuel cells catalyze the selective electrooxidation of renewable diols, simultaneously providing high power densities and chemicals of industrial importance. It is shown that the unique organometallic complex [Rh(OTf)(trop(2)NH)(PPh3)] employed as molecular active site in an anode of an OMFC selectively oxidizes a number of renewable diols, such as ethylene glycol, 1,2-propanediol (1,2-P), 1,3-propanediol (1,3-P), and 1,4-butanediol (1,4-B) to their corresponding mono-carboxylates. The electrochemical performance of this molecular catalyst is discussed, with the aim to achieve cogeneration of electricity and valuable chemicals in a highly selective electrooxidation from diol precursors. (literal)
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