Stabilization of Different Conformers of Bis(trifluoromethanesulfonyl)imide Anion in Ammonium-Based Ionic Liquids at Low Temperatures (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Stabilization of Different Conformers of Bis(trifluoromethanesulfonyl)imide Anion in Ammonium-Based Ionic Liquids at Low Temperatures (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/jp504833e (literal)

Alternative label

• F.M. Vitucci (1); F. Trequattrini (2); O. Palumbo (1); J.-B. Brubach (3); P. Roy (3); M. A. Navarra (4); S. Panero (4); A. Paolone (1) (2014)
  Stabilization of Different Conformers of Bis(trifluoromethanesulfonyl)imide Anion in Ammonium-Based Ionic Liquids at Low Temperatures
  in The journal of physical chemistry. A
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• F.M. Vitucci (1); F. Trequattrini (2); O. Palumbo (1); J.-B. Brubach (3); P. Roy (3); M. A. Navarra (4); S. Panero (4); A. Paolone (1) (literal)

Pagina inizio

• 8758 (literal)

Pagina fine

• 8764 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Publication Date (Web): September 4, 2014. (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021/jp504833e (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 118 (literal)

Rivista

• ?The ?journal of physical chemistry. A (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 38 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• (1) CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Roma, Italy (2) Physics Department and Chemistry Department, Sapienza University of Rome, Piazzale A. Moro 5, 00185 Roma, Italy (3) Synchrotron SOLEIL, F-91192 Gif Sur Yvette, France (literal)

Titolo

• Stabilization of Different Conformers of Bis(trifluoromethanesulfonyl)imide Anion in Ammonium-Based Ionic Liquids at Low Temperatures (literal)

Abstract

• The infrared absorption spectra of two ionic liquids with bis(trifluoromethanesulfonyl)imide (TFSI) as an anion and ammonium with different alkyl chains as cations are reported as a function of temperature. Using the comparison with ab initio calculations of the infrared-active intramolecular vibrations, the experimental lines were ascribed to the various ions composing the ionic liquids. In the liquid state of the samples, both conformers of the TFSI ion are present. In the solid state, however, the two conformers survive in N-trimethyl-N-propylammonium bis(trifluoromethanesulfonyl)imide (TMPA-TFSI), while only cis-TFSI is retained in N-trimethyl-N-hexylammonium bis(trifluoromethanesulfonyl)imide (TMHA-TFSI). We suggest that the longer alkyl chains of the former compound stabilize the less stable conformer of TFSI by means of stronger interactions between anions and cations. (literal)

Prodotto di

• La complessità nella fisica dello stato solido (MD.P02.011.001) (Modulo)

Autore CNR

• ANNALISA PAOLONE (Unità di personale interno)
• FRANCESCO MARIA VITUCCI (Persona)
• ORIELE PALUMBO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Stabilization of Different Conformers of Bis(trifluoromethanesulfonyl)imide Anion in Ammonium-Based Ionic Liquids at Low Temperatures" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• ANNALISA PAOLONE (Unità di personale interno)
• FRANCESCO MARIA VITUCCI (Persona)
• ORIELE PALUMBO (Unità di personale interno)

Prodotto

• La complessità nella fisica dello stato solido (MD.P02.011.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ?The ?journal of physical chemistry. A (Rivista)

Insieme di parole chiave di

• Keywords of "Stabilization of Different Conformers of Bis(trifluoromethanesulfonyl)imide Anion in Ammonium-Based Ionic Liquids at Low Temperatures" (Insieme di parole chiave)