http://www.cnr.it/ontology/cnr/individuo/prodotto/ID287522
The detection of copper resinate pigment in works of art: Contribution from Raman spectroscopy (Articolo in rivista)
- Type
- Label
- The detection of copper resinate pigment in works of art: Contribution from Raman spectroscopy (Articolo in rivista) (literal)
- Anno
- 2014-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/jrs.4455 (literal)
- Alternative label
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- Conti C.; Striova J.; Aliatis I.; Possenti E.; Massonnet G.; Muehlethaler C.; Poli T.; Positano M. (literal)
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- Istituto per la Conservazione e la Valorizzazione dei Beni Culturali (ICVBC) Consiglio Nazionale delle Ricerche (CNR) Via Cozzi 53 20125 Milano Italy; Consiglio Nazionale delle Ricerche (CNR), Istituto Nazionale di Ottica and LENS Università di Firenze Via Nello Carrara 1 50019 Sesto Fiorentino Italy; Dip. DIFEST Università di Parma Parco Area delle Scienze 7/A 43124 Parma Italy; School of Forensic Science (ESC), Institut de Police Scientifique University of Lausanne Batochime, UNIL-Sorge CH-1015 Lausanne-Dorigny Switzerland; Università degli Studi di Torino Dip. Chimica I.F.M., Via Giuria 7 10125 Torino Italy; Emmebi Diagnostica Artistica s.r.l. Via S.Francesco di Sales 80 00165 Roma Italy (literal)
- Titolo
- The detection of copper resinate pigment in works of art: Contribution from Raman spectroscopy (literal)
- Abstract
- Copper resinate is a green pigment widely used by the 16th century painters, as many surveys on Italian and European paintings proved. The pigment is a transparent green glaze, and its color is due to copper salts of resin acids. The oldest recipes suggest the preparation of copper resinate by mixing verdigris with terpenic resins as Venice turpentine (conifer resins) on hot ashes. The detection of copper resinate in paintings is up to this time an analytical challenge. We examined the Raman features of copper resinate (powder and in a mock paint film with linseed oil) and compared them with verdigris. Six laser sources (488, 514, 532, 633, 785, and 830nm) were used in different laboratories to highlight the drawbacks and advantages of a specific excitation source. The obtained results were applied in the analyses of a famous Caravaggio's painting. For a detailed interpretation and full exploitation of the Raman spectra, Fourier transform infrared spectroscopy measurements were carried out as well. © 2014 John Wiley & Sons, Ltd. (literal)
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