Mild and selective hydrogenation of aromatic and aliphatic (di) nitriles with a well-defined iron pincer complex (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Mild and selective hydrogenation of aromatic and aliphatic (di) nitriles with a well-defined iron pincer complex (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1038/ncomms5111 (literal)

Alternative label

• Bornschein, Christoph; Werkmeister, Svenja; Wendt, Bianca; Jiao, Haijun; Alberico, Elisabetta; Baumann, Wolfgang; Junge, Henrik; Junge, Kathrin; Beller, Matthias (2014)
  Mild and selective hydrogenation of aromatic and aliphatic (di) nitriles with a well-defined iron pincer complex
  in Nature communications
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bornschein, Christoph; Werkmeister, Svenja; Wendt, Bianca; Jiao, Haijun; Alberico, Elisabetta; Baumann, Wolfgang; Junge, Henrik; Junge, Kathrin; Beller, Matthias (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 5 (literal)

Rivista

• Nature communications (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 11 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• University of Rostock; Consiglio Nazionale delle Ricerche (CNR) (literal)

Titolo

• Mild and selective hydrogenation of aromatic and aliphatic (di) nitriles with a well-defined iron pincer complex (literal)

Abstract

• The catalytic hydrogenation of carboxylic acid derivatives represents an atom-efficient and clean reduction methodology in organic chemistry. More specifically, the selective hydrogenation of nitriles offers the possibility for a green synthesis of valuable primary amines. So far, this transformation lacks of useful, broadly applicable non-noble metal-based catalyst systems. In the present study, we describe a molecular-defined iron complex, which allows for the hydrogenation of aryl, alkyl, heterocyclic nitriles and dinitriles. By using an iron PNP pincer complex, we achieve very good functional group tolerance. Ester, ether, acetamido as well as amino substituents are not reduced in the presence of nitriles. Moreover, nitriles including an alpha,beta-unsaturated double bond and halogenated derivatives are well tolerated in this reaction. Notably, our complex constitutes the first example of an homogeneous catalyst, which permits the selective hydrogenation of industrially important adipodinitrile to 1,6-hexamethylenediamine. (literal)

Prodotto di

• Institute of biomolecular chemistry (ICB) (Istituto)
• Catalizzatori ad alta selettività in reazioni di idroformilazione ed idrogenazione (PM.P03.002.005) (Modulo)

Autore CNR

• ELISABETTA ALBERICO (Persona)

Incoming links:

Autore CNR di

• ELISABETTA ALBERICO (Persona)

Prodotto

• Institute of biomolecular chemistry (ICB) (Istituto)
• Catalizzatori ad alta selettività in reazioni di idroformilazione ed idrogenazione (PM.P03.002.005) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Nature communications (Rivista)