Ferromagnetic exchange coupling between Fe phthalocyanine and Ni(111) surface mediated by the extended states of graphene (Articolo in rivista)

Type
Label
  • Ferromagnetic exchange coupling between Fe phthalocyanine and Ni(111) surface mediated by the extended states of graphene (Articolo in rivista) (literal)
Anno
  • 2014-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp5041663 (literal)
Alternative label
  • A. Candini [ 1 ] ; Bellini V. [ 1 ] ; Klar D. [ 2,3 ] ; Corradini V. [ 1 ] ; Biagi R. [ 1,4 ] ; De Renzi V. [ 1,4 ] ; Kummer K. [ 5 ] ; Brookes N. B. [ 5 ] ; del Pennino U. [1,4 ] ; Wende H. [ 2,3 ] ; Affronte M. [ 1,4 ] (2014)
    Ferromagnetic exchange coupling between Fe phthalocyanine and Ni(111) surface mediated by the extended states of graphene
    in Journal of physical chemistry. C
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • A. Candini [ 1 ] ; Bellini V. [ 1 ] ; Klar D. [ 2,3 ] ; Corradini V. [ 1 ] ; Biagi R. [ 1,4 ] ; De Renzi V. [ 1,4 ] ; Kummer K. [ 5 ] ; Brookes N. B. [ 5 ] ; del Pennino U. [1,4 ] ; Wende H. [ 2,3 ] ; Affronte M. [ 1,4 ] (literal)
Pagina inizio
  • 17670 (literal)
Pagina fine
  • 17676 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.scopus.com/inward/record.url?eid=2-s2.0-84905841600&partnerID=q2rCbXpz (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 118 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 31 (literal)
Note
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • [ 1 ] CNR, Ist Nanosci, Ctr S3, I-41125 Modena, Italy [ 2 ] Univ Duisburg Essen, Fac Phys, D-47048 Duisburg, Germany [ 3 ] Univ Duisburg Essen, Ctr Nanointegrat Duisburg Essen CENIDE, D-47048 Duisburg, Germany [ 4 ] Univ Modena & Reggio Emilia, Dipartimento Sci Fis Informat & Matemat, I-41125 Modena, Italy [ 5 ] European Synchrotron Radiat Facil, F-38043 Grenoble 9, France (literal)
Titolo
  • Ferromagnetic exchange coupling between Fe phthalocyanine and Ni(111) surface mediated by the extended states of graphene (literal)
Abstract
  • The interface spin coupling mechanism is studied in a hybrid structure made of Fe phthalocyanine molecules sublimed in ultrahigh vacuum on graphene grown on the magnetic substrate Ni(111). By using synchrotron X-ray magnetic circular dichroism, the field-dependent magnetization of the isolated FePc molecules and of the Ni substrate has been measured at low temperature (8 K). Along with density functional theory calculations, the role of the graphene interlayer in transmitting the magnetic coupling is addressed. Both experiments and theory show a ferromagnetic coupling between the molecules and the substrate which is weakened by the insertion of graphene. DFT calculations indicate that the key role is played by the ? orbitals of graphene, which hybridize with the underlying magnetic Ni, giving rise to a sizable spin polarized continuum at the molecular interface. The resulting overlap with the Fe orbitals favors a direct coupling of ferromagnetic nature, as evidenced by our spin density distribution plots. © 2014 American Chemical Society. (literal)
Prodotto di
Autore CNR

Incoming links:


Autore CNR di
Prodotto
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
data.CNR.it