http://www.cnr.it/ontology/cnr/individuo/prodotto/ID284176
More Is Different: Experimental Results on the Effect of Biomolecules on the Dynamics of Hydration Water (Articolo in rivista)
- Type
- Label
- More Is Different: Experimental Results on the Effect of Biomolecules on the Dynamics of Hydration Water (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/jz400360v (literal)
- Alternative label
Comez, Lucia; Lupi, Laura; Morresi, Assunta; Paolantoni, Marco; Sassi, Paola; Fioretto, Daniele (2013)
More Is Different: Experimental Results on the Effect of Biomolecules on the Dynamics of Hydration Water
in The journal of physical chemistry letters
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Comez, Lucia; Lupi, Laura; Morresi, Assunta; Paolantoni, Marco; Sassi, Paola; Fioretto, Daniele (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- University of Perugia; University of Perugia; University of Perugia; University of Perugia (literal)
- Titolo
- More Is Different: Experimental Results on the Effect of Biomolecules on the Dynamics of Hydration Water (literal)
- Abstract
- Biological interfaces characterized by a complex mixture of hydrophobic, hydrophilic, or charged moieties interfere with the cooperative rearrangement of the hydrogen-bond network of water. In the present study, this solute-induced dynamical perturbation is investigated by extended frequency range depolarized light scattering experiments on an aqueous solution of a variety of systems of different nature and complexity such as small hydrophobic and hydrophilic molecules, amino acids, dipeptides, and proteins. Our results suggest that a reductionist approach is not adequate to describe the rearrangement of hydration water because a significant increase of the dynamical retardation and extension of the perturbation occurs when increasing the chemical complexity of the solute. (literal)
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