http://www.cnr.it/ontology/cnr/individuo/prodotto/ID283426
SiliaCat diphenylphosphine palladium(II) catalyzed borylation of aryl halides (Articolo in rivista)
- Type
- Label
- SiliaCat diphenylphosphine palladium(II) catalyzed borylation of aryl halides (Articolo in rivista) (literal)
- Anno
- 2014-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/cctc.201301035 (literal)
- Alternative label
Pandarus, Valerica; Marion, Olivier; Gingras, Geneviéve; Béland, François; Ciriminna, R.; Pagliaro, Mario (2014)
SiliaCat diphenylphosphine palladium(II) catalyzed borylation of aryl halides
in ChemCatChem (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Pandarus, Valerica; Marion, Olivier; Gingras, Geneviéve; Béland, François; Ciriminna, R.; Pagliaro, Mario (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://www.scopus.com/record/display.url?eid=2-s2.0-84900333059&origin=inward (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- SiliCycle Inc.; Istituto Per Lo Studio Dei Materiali Nanostrutturati, Rome (literal)
- Titolo
- SiliaCat diphenylphosphine palladium(II) catalyzed borylation of aryl halides (literal)
- Abstract
- We investigate the heterogeneously catalyzed direct synthesis of boronic acid pinacol esters using a wide range of aryl chlorides, bromides, and iodides, and bis(pinacolato)diboron as the borylating agent over the sol-gel entrapped SiliaCat diphenylphosphine palladium(II) catalyst. Optimization of the reaction conditions, scale-up of the optimized process, and analysis of palladium leaching enabled us to establish a new selective route for direct access to a diverse set of boronic acid pinacol esters. Clean borylation for scale-up: With the easy access and broad availability of diverse borylated species, the Suzuki-Miyaura reaction has become routine in industry and in research labs. We report a new selective route for direct access to a diverse set of boronic acid pinacol esters over the sol-gel entrapped SiliaCat diphenylphosphine palladium(II) catalyst that can be easily scaled-up. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. (literal)
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