Linear alpha-olefins obtained with palladium(II) complexes bearing a partially oxidized tetraphosphane (Articolo in rivista)

Type
Label
  • Linear alpha-olefins obtained with palladium(II) complexes bearing a partially oxidized tetraphosphane (Articolo in rivista) (literal)
Anno
  • 2014-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/om500573q (literal)
Alternative label
  • Oberhauser, Werner; Manca, Gabriele; Ienco, Andrea; Strabler, Christof; Prock, Johannes; Weninger, Alexander; Gutmann, Rene; Brueggeller, Peter; (2014)
    Linear alpha-olefins obtained with palladium(II) complexes bearing a partially oxidized tetraphosphane
    in Organometallics (Online)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Oberhauser, Werner; Manca, Gabriele; Ienco, Andrea; Strabler, Christof; Prock, Johannes; Weninger, Alexander; Gutmann, Rene; Brueggeller, Peter; (literal)
Pagina inizio
  • 4067 (literal)
Pagina fine
  • 4075 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 33 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 9 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICCOM-CNR Institut fuer Allgemeine, Anorganische und Theoretische Chemie, Universitaet Innsbruck (literal)
Titolo
  • Linear alpha-olefins obtained with palladium(II) complexes bearing a partially oxidized tetraphosphane (literal)
Abstract
  • The coordination of Pd(II) to the 1,3-trans- and 2,3- trans-dioxides and the trioxide of cis,trans,cis-1,2,3,4-tetrakis- (diphenylphosphino)cyclobutane gave two dinuclear Pd(II) complexes, which are structural isomers, and a mononuclear complex, respectively. The latter complexes proved to be suitable precatalysts for the oligomerization of ethylene to linear ?-olefins (98% selectivity). The different catalytic activity of the structural isomers was shown to depend on the dynamic behavior of the molecular structure. (literal)
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