Electronic structure of Mn-doped ZnO by x-ray emission and absorption spectroscopy (Articolo in rivista)

Type
Label
  • Electronic structure of Mn-doped ZnO by x-ray emission and absorption spectroscopy (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1088/0953-8984/20/27/275205 (literal)
Alternative label
  • Bondino, F; Garg, KB; Magnano, E; Carleschi, E; Heinonen, M; Singhal, RK; Gaur, SK; Parmigiani, F (2008)
    Electronic structure of Mn-doped ZnO by x-ray emission and absorption spectroscopy
    in Journal of physics. Condensed matter (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bondino, F; Garg, KB; Magnano, E; Carleschi, E; Heinonen, M; Singhal, RK; Gaur, SK; Parmigiani, F (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 20 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Laboratorio Nazionale TASC INFM-CNR, Basovizza-Trieste, Italy Department of Physics, University of Rajasthan, Jaipur-302004, India Dipartimento di Fisica, Universit`a degli Studi di Trieste, Trieste, Italy Department of Material Science, Turku University, Turku-20014, Finland (literal)
Titolo
  • Electronic structure of Mn-doped ZnO by x-ray emission and absorption spectroscopy (literal)
Abstract
  • We report an investigation of Mn-doped ZnO pellets with diluted Mn concentration by soft-x-ray emission and absorption spectroscopy. We have compared the electronic structure of two samples with different Mn concentration and different magnetic properties at room temperature: ferromagnetism in one case (Zn0.98Mn0.02O) and no magnetic order in the other (Zn0.96Mn0.04O). The results show that most of the Mn ions of the ferromagnetic sample are in the divalent state. For the nonmagnetic sample, a larger contribution of higher oxidation Mn states is present, which can be correlated to the suppressed ferromagnetism. The presence of oxygen atoms bonded to Mn ions and hybridized Mn 3d-O 2p states has been detected in both compounds. The partial density of states in the valence band has been measured with x-ray emission spectroscopy and the Mn 3d states have been found inside the bandgap of ZnO. (literal)
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