Synthesis and photochemical behaviour of novel uranyl-salophen complexes bearing anthracenyl side arms (Articolo in rivista)

Type
Label
  • Synthesis and photochemical behaviour of novel uranyl-salophen complexes bearing anthracenyl side arms (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1080/10610278.2012.752089 (literal)
Alternative label
  • F. Yafteh Mihan, S. Bartocci, A. Credi, S. Silvi, A. Dalla Cort (2013)
    Synthesis and photochemical behaviour of novel uranyl-salophen complexes bearing anthracenyl side arms
    in Supramolecular chemistry (Print); Taylor and Francis, Abingdon (Regno Unito)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • F. Yafteh Mihan, S. Bartocci, A. Credi, S. Silvi, A. Dalla Cort (literal)
Pagina inizio
  • 109 (literal)
Pagina fine
  • 115 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.tandfonline.com/loi/gsch20 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 25 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 7 (literal)
Note
  • ISI Web of Science (WOS) (literal)
  • Scopus (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Department of Chemistry and IMC-CNR, Università La Sapienza, Piazzale Aldo Moro 5, 00185, Roma, Italy Photochemical Nanosciences Laboratory and Center for the Chemical Conversion of Solar Energy (SolarChem), Dipartimento di Chimica 'Giacomo Ciamician', Università di Bologna, via Selmi 2, 40126, Bologna, Italy (literal)
Titolo
  • Synthesis and photochemical behaviour of novel uranyl-salophen complexes bearing anthracenyl side arms (literal)
Abstract
  • In this paper, we report the synthesis and physico-chemical investigation of two uranyl-salophen receptors, bearing either one or two anthracenyl moieties appended to the salophen skeleton. Despite the presence of the anthracenyl fluorophores, no fluorescence emission was detected. Photophysical data and cyclic voltammetric experiments show that photoinduced electron transfer from the anthracene-localised first singlet excited state to the metal centre is strongly exergonic, thus suggesting that this is the main fluorescence quenching mechanism in these complexes. The investigated compounds are photoreactive upon UV irradiation, yielding either anthracene photooxidation or photodimerisation products depending on the specific complex and the experimental conditions. (literal)
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