http://www.cnr.it/ontology/cnr/individuo/prodotto/ID276087
Speciation analysis of mercury in seawater from the lagoon of Venice by on-line pre-concentration HPLC-ICP-MS (Articolo in rivista)
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- Speciation analysis of mercury in seawater from the lagoon of Venice by on-line pre-concentration HPLC-ICP-MS (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.aca.2008.05.048 (literal)
- Alternative label
Cairns, W.R.L., Ranaldo, M., Hennebelle, R., Turetta, C., Capodaglio, G., Ferrari, C.F., Dommergue, A., Cescon, P., Barbante, C. (2008)
Speciation analysis of mercury in seawater from the lagoon of Venice by on-line pre-concentration HPLC-ICP-MS
in Analytica chimica acta (Print)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Cairns, W.R.L., Ranaldo, M., Hennebelle, R., Turetta, C., Capodaglio, G., Ferrari, C.F., Dommergue, A., Cescon, P., Barbante, C. (literal)
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- cited By (since 1996)27 (literal)
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- Institute for the Dynamics, Environmental Processes-CNR, Calle Larga Santa Marta 2137, 30123 Venice, Italy; Department of Environmental Sciences, University Ca' Foscari, Calle Larga Santa Marta 2137, 30123 Venezia, Italy; Laboratoire de Glaciologie et de G (literal)
- Titolo
- Speciation analysis of mercury in seawater from the lagoon of Venice by on-line pre-concentration HPLC-ICP-MS (literal)
- Abstract
- A method based on the coupling of HPLC with ICP-MS with an on-line pre-concentration micro-column has been developed for the analysis of inorganic and methyl mercury in the dissolved phase of natural waters. This method allows the rapid pre-concentration and matrix removal of interferences in complex matrices such as seawater with minimal sampling handling. Detection limits of 0.07 ng L -1 for inorganic mercury and 0.02 ng L -1 for methyl mercury have been achieved allowing the determination of inorganic mercury and methyl mercury in filtered seawater from the Venice lagoon. Good accuracy and reproducibility was demonstrated by the repeat analysis of the certified reference material BCR-579 coastal seawater. The developed HPLC separation was shown to be also suitable for the determination of methyl mercury in extracts of the particulate phase. (literal)
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