Titanium complexes bearing carbamato ligands as catalytic precursors for propylene polymerization reactions (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Titanium complexes bearing carbamato ligands as catalytic precursors for propylene polymerization reactions (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/pola.26816 (literal)

Alternative label

• Mohammad Hayatifar, Claudia Forte, Guido Pampaloni, Yury V. Kissin, Anna Maria Raspolli Galletti, Stefano Zacchini (2013)
  Titanium complexes bearing carbamato ligands as catalytic precursors for propylene polymerization reactions
  in Journal of polymer science. Part A, Polymer chemistry; WILEY-BLACKWELL, 111 RIVER ST, HOBOKEN 07030-5774, NJ (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Mohammad Hayatifar, Claudia Forte, Guido Pampaloni, Yury V. Kissin, Anna Maria Raspolli Galletti, Stefano Zacchini (literal)

Pagina inizio

• 4095 (literal)

Pagina fine

• 4102 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 51 (literal)

Rivista

• Journal of polymer science. Part A, Polymer chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 19 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Univ Pisa, Dept Chim & Chim Ind, I-56126 Pisa, Italy CNR, ICCOM, Area Ric, I-56124 Pisa, Italy Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA Univ Bologna, Dipartimento Chim Ind Toso Montanari, I-40136 Bologna, Italy (literal)

Titolo

• Titanium complexes bearing carbamato ligands as catalytic precursors for propylene polymerization reactions (literal)

Abstract

• This report describes propylene polymerization reactions with titanium complexes bearing carbamato ligands, Ti(O2CNMe2)Cl2 (I) and Ti(O2CR2)4 [R2 = NMe2 (II), NEt2 (III) and image (IV)]. Combinations of these complexes and MAO form catalysts for the synthesis of atactic polypropylene, as confirmed by FT-IR, DSC and 13C NMR analysis. Effects of main reaction parameters on the catalyst activity were studied including the type of complex, solvent, temperature, and the [Al]/[Ti] molar ratio. The highest activity was observed when chlorobenzene was used as a solvent and AlMe3-depleted MAO was employed as a cocatalyst. (literal)

Editore

• WILEY-BLACKWELL (Editore)

Prodotto di

• Spettroscopie di risonanza magnetica applicata alla scienza dei materiali (MD.P03.035.002) (Modulo)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• CLAUDIA FORTE (Persona)

Insieme di parole chiave

• Parole chiave di "Titanium complexes bearing carbamato ligands as catalytic precursors for propylene polymerization reactions" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Spettroscopie di risonanza magnetica applicata alla scienza dei materiali (MD.P03.035.002) (Modulo)

Autore CNR di

• CLAUDIA FORTE (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of polymer science. Part A, Polymer chemistry (Rivista)

Editore di

• WILEY-BLACKWELL (Editore)

Insieme di parole chiave di

• Parole chiave di "Titanium complexes bearing carbamato ligands as catalytic precursors for propylene polymerization reactions" (Insieme di parole chiave)