Fluorine-Induced Enhancement of the Oxidation Stability and Deep-Blue Optical Activity in Conductive Polyfluorene Derivatives (Articolo in rivista)

Type
Label
  • Fluorine-Induced Enhancement of the Oxidation Stability and Deep-Blue Optical Activity in Conductive Polyfluorene Derivatives (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp409996m (literal)
Alternative label
  • Calzolari A.; Vercelli B.; Ruini A.; Virgili T.; Pasini M. (2013)
    Fluorine-Induced Enhancement of the Oxidation Stability and Deep-Blue Optical Activity in Conductive Polyfluorene Derivatives
    in Journal of physical chemistry. C; American Chemical Society, Washington (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Calzolari A.; Vercelli B.; Ruini A.; Virgili T.; Pasini M. (literal)
Pagina inizio
  • 26760 (literal)
Pagina fine
  • 26767 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://pubs.acs.org/doi/abs/10.1021/jp409996m (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 117 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 50 (literal)
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1,3 : CNR-NANO Istituto Nanoscienze, Centro S3, I-41125 Modena, Italy / 1 : Physics Department, University of North Texas, Denton, TX 76203, United States / 2 : Istituto CNR per l'Energetica e le Interfasi, I-20125 Milano, Italy / 3 : Dipartimento di Fisica, Informatica e Matematica, Università di Modena e Reggio Emilia, I-41125 Modena, Italy / 4 : Istituto CNR di Fotonica e Nanotecnologie, 20132 Milano, Italy / 5 : Istituto CNR per Lo Studio Delle Macromolecole, 21133 Milano, Italy (literal)
Titolo
  • Fluorine-Induced Enhancement of the Oxidation Stability and Deep-Blue Optical Activity in Conductive Polyfluorene Derivatives (literal)
Abstract
  • We present a joint experimental/theoretical study on the effects of fluorination on structural, electronic, and optical properties of poly[(9,9-di-n-octylfluoren-2,7-diyl)-alt-tetrafluoro-p-phenylene] (PFTFP), a polyfluorene (PFO)-derived conjugated polymer. The combination of optical (UV-vis) and electrochemical (cyclic voltammetry) techniques with atomistic simulations demonstrates an improved oxidative stability of the fluorinated compound with respect to standard PFO. The resulting excellent luminescence efficiency along with the preservation of the good charge mobility, characteristic of the pristine PFO, make PFTFP a superior material for optoelectronic applications in the deep-blue. The comparison with auxiliary model systems provides a microscopic identification of the peculiar effects of fluorine on the structural and electronic properties of the polymer. (literal)
Editore
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Autore CNR di
Prodotto
Editore di
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Insieme di parole chiave di
data.CNR.it