Vinylogous Aldol Reaction of a Silyloxydiene Promoted by Sulfoxides, as Lewis Bases: 1,4-asymmetric Induction Mediated by a Remote Methylsulfinyl Group (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Vinylogous Aldol Reaction of a Silyloxydiene Promoted by Sulfoxides, as Lewis Bases: 1,4-asymmetric Induction Mediated by a Remote Methylsulfinyl Group (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Alternative label

• Maria Rosaria Acocella, Rosaria Villano, Chiara Costabile, Arrigo Scettri (2013)
  Vinylogous Aldol Reaction of a Silyloxydiene Promoted by Sulfoxides, as Lewis Bases: 1,4-asymmetric Induction Mediated by a Remote Methylsulfinyl Group
  in Current organic chemistry
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Maria Rosaria Acocella, Rosaria Villano, Chiara Costabile, Arrigo Scettri (literal)

Pagina inizio

• 886 (literal)

Pagina fine

• 890 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 17 (literal)

Rivista

• Current organic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 8 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Università di Salerno, Dipartimento di Chimica e Biologia - Fisciano (SA) Istituto di Chimica Biomolecolare, CNR - Sassari (literal)

Titolo

• Vinylogous Aldol Reaction of a Silyloxydiene Promoted by Sulfoxides, as Lewis Bases: 1,4-asymmetric Induction Mediated by a Remote Methylsulfinyl Group (literal)

Abstract

• A versatile procedure for the gamma-vinylogous aldol reaction of the dioxinone-derived silyl enolether, via enolate activation with an appropriate neutral Lewis base, was formulated. High levels of diastereo- and enantioselectivity using chiral 2-methylsulfinyl benzaldehyde were obtained, pointing out the dual role of the methylsulfinyl group as incorporated chiral inductor and activator of the silyloxydiene in the stereoselective vinylogous aldol reaction. (literal)

Prodotto di

• Institute of biomolecular chemistry (ICB) (Istituto)
• Metodologie sintetiche a base multisettoriale per la costruzione di strutture molecolari complesse (PM.P01.011.005) (Modulo)

Autore CNR

• ROSARIA VILLANO (Unità di personale interno)

Incoming links:

Autore CNR di

• ROSARIA VILLANO (Unità di personale interno)

Prodotto

• Institute of biomolecular chemistry (ICB) (Istituto)
• Metodologie sintetiche a base multisettoriale per la costruzione di strutture molecolari complesse (PM.P01.011.005) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Current organic chemistry (Rivista)