Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/nn4035684 (literal)

Alternative label

• Di Giovannantonio Marco, El Garah Mohamed, Lipton-Duffin Josh, Meunier Vincent, Cardenas Luis, Fagot Revurat Yannick, Cossaro Albano, Verdini Alberto, Perepichka Dmitrii F., Rosei Federico, Contini Giorgio (2013)
  Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization
  in ACS nano
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Di Giovannantonio Marco, El Garah Mohamed, Lipton-Duffin Josh, Meunier Vincent, Cardenas Luis, Fagot Revurat Yannick, Cossaro Albano, Verdini Alberto, Perepichka Dmitrii F., Rosei Federico, Contini Giorgio (literal)

Pagina inizio

• 8190 (literal)

Pagina fine

• 8198 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021/nn4035684 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 7 (literal)

Rivista

• ACS nano (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 9 (literal)

Note

• Scopus (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Struttura della Materia, CNR, Via Fosso del Cavaliere 100, 00133 Roma, Italy Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, QC J3X 1S2, Canada Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, 110 8th Street, Troy, New York 12180, United States Institut Jean Lamour, UMR 7198, Université Lorraine/CNRS, B.P. 239 FE-54506, Vandoeuvre-les-Nancy, France IOM-CNR, Laboratorio TASC, 34149 Trieste, Italy Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, Montreal, QC H3A 2K6, Canada Department of Physics and Centro Interdipartimentale Nanoscienze & Nanotecnologie & Strumentazione (NAST), University of Rome \"Tor Vergata\", 00133 Roma, Italy (literal)

Titolo

• Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization (literal)

Abstract

• We provide insight into surface-catalyzed dehalogenative polymerization, analyzing the organometallic intermediate and its evolution into planar polymeric structures. A combined study using scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), low energy electron diffraction (LEED), near-edge X-ray absorption fine structure (NEXAFS) spectroscopy and first-principles calculations unveils the structural conformation of substrate-bound phenylene intermediates generated from 1,4-dibromobenzene precursors on Cu(110), showing the stabilizing role of the halogen. The appearance of covalently bonded conjugated structures is followed in real time by fast-XPS measurements (with an acquisition time of 2 s per spectrum and heating rate of 2 K/s), showing that the detaching of phenylene units from the copper substrate and subsequent polymerization occur upon annealing above 460 ± 10 K. (literal)

Prodotto di

• 2D molecular devices and superconductors (MD.P06.005.002) (Modulo)
• Institute of structure of matter (ISM) (Istituto)

Autore CNR

• GIORGIO CONTINI (Unità di personale interno)
• ALBERTO VERDINI (Unità di personale interno)
• ALBANO COSSARO (Persona)

Incoming links:

Autore CNR di

• GIORGIO CONTINI (Unità di personale interno)
• ALBANO COSSARO (Persona)
• ALBERTO VERDINI (Unità di personale interno)

Prodotto

• Institute of structure of matter (ISM) (Istituto)
• 2D molecular devices and superconductors (MD.P06.005.002) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ACS nano (Rivista)