Fully aliphatic copolyesters based on poly(butylene 1,4- cyclohexanedicarboxylate) with promising mechanical and barrier properties for food packaging applications (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Fully aliphatic copolyesters based on poly(butylene 1,4- cyclohexanedicarboxylate) with promising mechanical and barrier properties for food packaging applications (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ie401781d (literal)

Alternative label

• Gigli, M.a and Lotti, N.a and Gazzano, M.b and Siracusa, V.c and Finelli, L.a and Munari, A.a and Dalla Rosa, M.d (2013)
  Fully aliphatic copolyesters based on poly(butylene 1,4- cyclohexanedicarboxylate) with promising mechanical and barrier properties for food packaging applications
  in Industrial & engineering chemistry research
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Gigli, M.a and Lotti, N.a and Gazzano, M.b and Siracusa, V.c and Finelli, L.a and Munari, A.a and Dalla Rosa, M.d (literal)

Pagina inizio

• 12876 (literal)

Pagina fine

• 12886 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• cited By (since 1996)0 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.scopus.com/inward/record.url?eid=2-s2.0-84884173620&partnerID=40&md5=fac0b8ab2047c96c327526432022c08c (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 52 (literal)

Rivista

• Industrial & engineering chemistry research (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 36 (literal)

Note

• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dipartimento di Ingegneria Civile, Ambientale e Dei Materiali, Università di Bologna, Via Terracini 28, 40131 Bologna, Italy; Istituto per la Sintesi Organica e la Fotoreattività, CNR, Via Selmi 2, 40126 Bologna, Italy; Dipartimento di Ingegneria Industriale, Università di Catania, Viale A. Doria 6, 95125 Catania, Italy; Dipartimento di Scienze e Tecnologie Agro-Alimentari, Università di Bologna, Piazza Goidanich 60, 47521 Cesena, Italy (literal)

Titolo

• Fully aliphatic copolyesters based on poly(butylene 1,4- cyclohexanedicarboxylate) with promising mechanical and barrier properties for food packaging applications (literal)

Abstract

• Poly(butylene cyclohexanedicarboxylate/diglycolate) random copolymers (P(BCEmBDGn)) of various compositions were synthesized and characterized from the molecular, thermal, structural, and mechanical point of view. Barrier properties to different gases (oxygen and carbon dioxide) were also evaluated. All the polymers showed good thermal stability and appeared as semicrystalline materials at room temperature. The main effect of copolymerization was a lowering in the crystallinity and a decrease of Tm with respect to homopolymers. The dependence of Tm on composition for copolymers with high butylene cyclohexanedicarboxylate unit content was well described by Baur's equation. X-ray diffraction (XRD) measurements indicated that two different crystalline phases are present, depending on composition: copolymers with high BCE unit content were characterized by PBCE crystal phase, whereas those rich in BDG counits crystallized in PBDG lattice. The samples displayed different surface hydrophilicity: the water contact angle regularly decreased with the increasing mol % of BDG. The mechanical properties were found strictly related to crystallinity degree (?c); the copolymers containing 60-75 mol % of BDG showed the lowest elastic modulus and the highest elongation at break. Lastly, the chemical composition of the copolymer strongly influenced permeability to CO2 and O2. Moreover, the selectivity ratios for the examined samples increased with the increasing of BDG mol %, confirming the existence of a correlation between the permeability and the chemical composition. Almost all copolymers showed improved barrier properties with respect to polylactide films tested under the same conditions. © 2013 American Chemical Society. (literal)

Prodotto di

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Polimerizzazione radicalica controllata e caratterizzazione avanzata di nuovi materiali polimerici (PRACCAMPO) (PM.P02.016.001) (Modulo)

Autore CNR

• MASSIMO GAZZANO (Persona)

Insieme di parole chiave

• Parole chiave di "Fully aliphatic copolyesters based on poly(butylene 1,4- cyclohexanedicarboxylate) with promising mechanical and barrier properties for food packaging applications" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Polimerizzazione radicalica controllata e caratterizzazione avanzata di nuovi materiali polimerici (PRACCAMPO) (PM.P02.016.001) (Modulo)

Autore CNR di

• MASSIMO GAZZANO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Industrial & engineering chemistry research (Rivista)

Insieme di parole chiave di

• Parole chiave di "Fully aliphatic copolyesters based on poly(butylene 1,4- cyclohexanedicarboxylate) with promising mechanical and barrier properties for food packaging applications" (Insieme di parole chiave)