Spontaneous Assembly of Carbon-Based Chains in Polymer Matrices through Surface Charge Templates (Articolo in rivista)

Type
Label
  • Spontaneous Assembly of Carbon-Based Chains in Polymer Matrices through Surface Charge Templates (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/la403603d (literal)
Alternative label
  • O. Gennari, S. Grilli, S. Coppola, V. Pagliarulo, V. Vespini, G. Coppola, S. Bhowmick, M. A. Gioffré, G. Gentile, V. Ambrogi, P. Cerruti, C. Carfagna, P. Ferraro (2013)
    Spontaneous Assembly of Carbon-Based Chains in Polymer Matrices through Surface Charge Templates
    in Langmuir; ACS, American chemical society, Washington, DC (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • O. Gennari, S. Grilli, S. Coppola, V. Pagliarulo, V. Vespini, G. Coppola, S. Bhowmick, M. A. Gioffré, G. Gentile, V. Ambrogi, P. Cerruti, C. Carfagna, P. Ferraro (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • National Institute of Optics, National Council of Research of Italy, Via Campi Flegrei 34, 80078 Pozzuoli, Italy Institute of Microelectronics and Microsystems, National Council of Research of Italy, Via Pietro Castellino, Napoli, Italy Institute of Polymer Chemistry and Technology, National Council of Research of Italy, Via Campi Flegrei 34, 80078 Pozzuoli, Italy Department of Chemical, Materials and Production Engineering, University of Naples, Piazzale Tecchio, 80125 Naples, Italy (literal)
Titolo
  • Spontaneous Assembly of Carbon-Based Chains in Polymer Matrices through Surface Charge Templates (literal)
Abstract
  • Stable chains of carbon-based nanoparticles were formed directly in polymer matrices through an electrode-free approach. Spontaneous surface charges were generated pyroelectrically onto functionalized ferroelectric crystals, enabling the formation of electric field gradients that triggered the dipole-dipole interactions responsible for the alignment of the particles, while embedded in the polymer solution. The phenomenon is similar to the dielectrophoretic alignment of carbon nanotubes reported in literature. However, here the electric fields are generated spontaneously by a simple heat treatment that, simultaneously, align the particles and provides the energy necessary for curing the host polymer. The result is a polymer sheet reinforced with well-aligned chains of carbon-based particles avoiding the invasive implementation of appropriate electrodes and circuits. Since polymers with anisotropic features are of great interest for enhancing the thermal and/or the electrical conductivity, the electrode-free nature of this technique would improve the scaling down and the versatility of those interconnections that find applications in many fields, such as electronics, sensors and biomedicine. Theoretical simulations of the interactions between the particles and the charge templates were implemented and appear in good agreement with the experimental results. The chain formation was characterized by controlling different parameters, including surface charge configuration, particle concentration and polymer viscosity, thus demonstrating the reliability of the technique. Moreover, micro-Raman spectroscopy and scanning electron microscopy were used for a deep inspection of the assembled chains. (literal)
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