Photocatalysis with Na4W10O32 in water system: Formation and reactivity of OH center dot radicals (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Photocatalysis with Na4W10O32 in water system: Formation and reactivity of OH center dot radicals (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.molcata.2013.01.037 (literal)

Alternative label

• Molinari, Alessandra and Argazzi, Roberto and Maldotti, Andrea (2013)
  Photocatalysis with Na4W10O32 in water system: Formation and reactivity of OH center dot radicals
  in Journal of molecular catalysis. A, Chemical (Print); ELSEVIER SCIENCE B.V., AMSTERDAM (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Molinari, Alessandra and Argazzi, Roberto and Maldotti, Andrea (literal)

Pagina inizio

• 23 (literal)

Pagina fine

• 28 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 372 (literal)

Rivista

• Journal of molecular catalysis. A, Chemical (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 6 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Molinari, A (Reprint Author), Univ Ferrara, Dipartimento Chim, Via Luigi Borsari 46, I-44123 Ferrara, Italy. Molinari, Alessandra; Maldotti, Andrea, Univ Ferrara, Dipartimento Chim, I-44123 Ferrara, Italy. Argazzi, Roberto, Ctr ISOF CNR, I-44123 Ferrara, Italy. (literal)

Titolo

• Photocatalysis with Na4W10O32 in water system: Formation and reactivity of OH center dot radicals (literal)

Abstract

• Photoexcitation of Na4W10O32 dissolved in water leads to the formation of hydroxyl radicals. These species originate both from H2O oxidation and H2O2 reduction. EPR-spin trapping investigation and laser flash photolysis experiments contribute to clarify their formation mechanism and their involvement in the oxidation of propan-2-ol. Continuous irradiation of water solutions of Na4W10O32 leads to the overoxidation of propan-2-ol to CO2 with high yield. This result may be of interest for the development of photocatalytic systems aimed to pollutants degradation. Entrapment of Na4W10O32 into a microporous silica matrix gives a rather robust photocatalyst where the decatungstate structure is preserved. This material is able to catalyze the photooxidation of propan-2-ol to acetone with appreciable chemoselectivity. In particular, it is seen that the solid photocatalyst yields acetone as main product inhibiting its over-oxidation to carbon dioxide. (C) 2013 Elsevier B.V. All rights reserved. (literal)

Editore

• ELSEVIER SCIENCE B.V. (Editore)

Prodotto di

• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Autore CNR

• ROBERTO ARGAZZI (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Photocatalysis with Na4W10O32 in water system: Formation and reactivity of OH center dot radicals" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR di

• ROBERTO ARGAZZI (Unità di personale interno)

Editore di

• ELSEVIER SCIENCE B.V. (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of molecular catalysis. A, Chemical (Rivista)

Insieme di parole chiave di

• Keywords of "Photocatalysis with Na4W10O32 in water system: Formation and reactivity of OH center dot radicals" (Insieme di parole chiave)