Aqueous and Solvent-Free Uncatalyzed Three-Component Vinylogous Mukaiyama-Mannich Reactions of Pyrrole-Based Silyl Dienolates (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Aqueous and Solvent-Free Uncatalyzed Three-Component Vinylogous Mukaiyama-Mannich Reactions of Pyrrole-Based Silyl Dienolates (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/adsc.201100572 (literal)

Alternative label

• Andrea Sartori, Luca Dell'Amico, Claudio Curti, Lucia Battistini, Giorgio Pelosi, Gloria Rassu, Giovanni Casiraghi and Franca Zanardi (2011)
  Aqueous and Solvent-Free Uncatalyzed Three-Component Vinylogous Mukaiyama-Mannich Reactions of Pyrrole-Based Silyl Dienolates
  in Advanced synthesis & catalysis (Internet); Wiley-Blackwell, Oxford (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Andrea Sartori, Luca Dell'Amico, Claudio Curti, Lucia Battistini, Giorgio Pelosi, Gloria Rassu, Giovanni Casiraghi and Franca Zanardi (literal)

Pagina inizio

• 3278 (literal)

Pagina fine

• 3284 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1615-4169 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 353 (literal)

Rivista

• Advanced synthesis & catalysis (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 18 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Università degli Studi di Parma Consiglio Nazionale delle Ricerche (literal)

Titolo

• Aqueous and Solvent-Free Uncatalyzed Three-Component Vinylogous Mukaiyama-Mannich Reactions of Pyrrole-Based Silyl Dienolates (literal)

Abstract

• A catalyst-free, environmentally benign three-component vinylogous Mukaiyama-Mannich reaction of pyrrole-based silyl dienolates is presented, which works effectively in both aqueous and solvent-free environments. Both lipophilic and hydrophilic aldehyde candidates are suitable substrates, allowing access to a rich repertoire of unsaturated vicinal aminolactam structures with virtually complete g-site selectivity and moderate to good anti-diastereoselectivity. The utility of this technology is highlighted by protecting group-free synthesis of densely hydroxylated, sugar-related lactam frameworks. The role of water as an indispensable H-bonding reaction propeller is demonstrated. (literal)

Editore

• Wiley-Blackwell (Editore)

Prodotto di

• Istituto di chimica biomolecolare (ICB) (Istituto)

Autore CNR

• GLORIA MARIA RITA RASSU (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Aqueous and Solvent-Free Uncatalyzed Three-Component Vinylogous Mukaiyama-Mannich Reactions of Pyrrole-Based Silyl Dienolates" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• GLORIA MARIA RITA RASSU (Unità di personale interno)

Prodotto

• Istituto di chimica biomolecolare (ICB) (Istituto)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Advanced synthesis & catalysis (Rivista)

Editore di

• Wiley-Blackwell (Editore)

Insieme di parole chiave di

• Keywords of "Aqueous and Solvent-Free Uncatalyzed Three-Component Vinylogous Mukaiyama-Mannich Reactions of Pyrrole-Based Silyl Dienolates" (Insieme di parole chiave)