Fast dissociation of resonantly core excited H2S studied by vibrational and temporal analysis of the Auger spectra (Articolo in rivista)

Type
Label
  • Fast dissociation of resonantly core excited H2S studied by vibrational and temporal analysis of the Auger spectra (Articolo in rivista) (literal)
Anno
  • 1997-01-01T00:00:00+01:00 (literal)
Alternative label
  • Arnaldo Naves de Brito, Alexandre Naves de Brito, Olle Björneholm, Joaquim Soares Neto, AndréBueno Machado, Svante Svensson, Andrus Ausmees, Stuart J. Osborne, Leif J. Sæthre, Helena Aksela, Olli-Pekka Sairanen, Antti Kivimäki, Ergo Nõmmiste, Seppo Aksela (1997)
    Fast dissociation of resonantly core excited H2S studied by vibrational and temporal analysis of the Auger spectra
    in Journal of molecular structure (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Arnaldo Naves de Brito, Alexandre Naves de Brito, Olle Björneholm, Joaquim Soares Neto, AndréBueno Machado, Svante Svensson, Andrus Ausmees, Stuart J. Osborne, Leif J. Sæthre, Helena Aksela, Olli-Pekka Sairanen, Antti Kivimäki, Ergo Nõmmiste, Seppo Aksela (literal)
Pagina inizio
  • 135 (literal)
Pagina fine
  • 145 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://dx.doi.org/10.1016/S0166-1280(96)04828-2 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 394 (literal)
Rivista
Note
  • Scopus (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Department of Physics, University of Brasilia, 70910-900 Brasilia DF, Brazil Department of Physics, Uppsala University, Box 530, S-752 21 Uppsala, Sweden Department of Chemistry, University of Bergen, N-5007 Bergen, Norway Department of Physical Sciences, Oulu University, FIN-90570 Oulu, Finland (literal)
Titolo
  • Fast dissociation of resonantly core excited H2S studied by vibrational and temporal analysis of the Auger spectra (literal)
Abstract
  • Excitation of a core electron to the lowest unoccupied orbital of H2S has been shown to give rise to dissociation that occurs faster than the Auger decay. Recent experimental data have allowed us to resolve vibrational structures connected with the resonant Auger decay in the core excited S*H fragment. At some photon energies, hot bands resulting from the decay of the vibrationally excited levels, v = 1 andv = 2, in the core excited fragment are observed. A new generalised potential energy surface for the 2p-16a1 state of H2S is presented. Calculations of the vibrationally excited states at different points through the dissociation channel of the potential energy surface are presented. These allow determination of the point on the surface which has vibrational splitting consistent with the experimental values, revealing the geometry of the fragment when the core excited state decays. A new method, based on the core hole lifetime as an internal \"stop-watch\", to determine the characteristic time for dissociation of the H2S* molecule into H and S* H fragments from experimental data is presented. This result is compared with values obtained using the potential energy surface calculations. (literal)
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