http://www.cnr.it/ontology/cnr/individuo/prodotto/ID268428
Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis (Articolo in rivista)
- Type
- Label
- Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1039/c3dt51620b (literal)
- Alternative label
Luconi, Lapo; Klosin, Jerzy; Smith, Austin J.; Germain, Stéphane;
Schulz, Emmanuelle; Hannedouche, Jérôme; Giambastiani, Giuliano (2013)
Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis
in Dalton transactions (2003. Online); RSC Publishing, Cambridge (Regno Unito)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Luconi, Lapo; Klosin, Jerzy; Smith, Austin J.; Germain, Stéphane;
Schulz, Emmanuelle; Hannedouche, Jérôme; Giambastiani, Giuliano (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
- Issue front cover (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Institute of Chemistry of OrganoMetallic Compounds ICCOM-CNR, Via Madonna del Piano, 10-50019 Sesto F.no., Florence, Italy.
Corporate R&D, The Dow Chemical Company, 1776 Building, Midland, MI 48674, USA
Equipe de Catalyse Moleculaire, Université Paris-Sud, ICMMO, UMR 8182, Orsay, F-91405, France & CNRS, Orsay, F-91405, France (literal)
- Titolo
- Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis (literal)
- Abstract
- Neutral ZrIV and HfIV dimethyl complexes stabilized by unsymmetrical dianionic {N,C,N'} pincer ligands
have been prepared from their corresponding bis-amido complexes upon treatment with AlMe3. Their
structure consists of a central ?-bonded aryl donor group (C) capable of forming robust M-C bonds with
the metal center, enforced by the synergic effect of both the coordination of peripheral donor groups
(N) and the chelating rigid structure of the {N,C,N} ligand framework. Such a combination translates into
systems having a unique balance between stability and reactivity. These ZrIV and HfIV dimethyl complexes
were converted in situ into cationic species [MIV{N-,C-,N}Me][B(C6F5)4] which are active catalysts for the
room temperature (r.t.) intramolecular hydroamination/cyclization of primary and secondary aminoalkenes
as well as for the high temperature ethylene-1-octene copolymerizations. (literal)
- Editore
- Prodotto di
- Autore CNR
Incoming links:
- Prodotto
- Autore CNR di
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
- Editore di