Switch On/Switch Off Signal in an MOF-Guest Crystalline Device (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Switch On/Switch Off Signal in an MOF-Guest Crystalline Device (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/ejic.201300533 (literal)

Alternative label

• Mazzeo, Paolo P. and Maini, Lucia and Braga, Dario and Valenti, Giovanni and Paolucci, Francesco and Marcaccio, Massimo and Barbieri, Andrea and Ventura, Barbara (2013)
  Switch On/Switch Off Signal in an MOF-Guest Crystalline Device
  in European journal of inorganic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Mazzeo, Paolo P. and Maini, Lucia and Braga, Dario and Valenti, Giovanni and Paolucci, Francesco and Marcaccio, Massimo and Barbieri, Andrea and Ventura, Barbara (literal)

Pagina inizio

• 4459 (literal)

Pagina fine

• 4465 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 2013 (literal)

Rivista

• European journal of inorganic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 25 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Maini, L (Reprint Author), Univ Bologna, Dept Chem G Ciamician, Via Francesco Selmi 2, I-40126 Bologna, Italy. Mazzeo, Paolo P.; Maini, Lucia; Braga, Dario; Valenti, Giovanni; Paolucci, Francesco; Marcaccio, Massimo, Univ Bologna, Dept Chem G Ciamician, I-40126 Bologna, Italy. Barbieri, Andrea; Ventura, Barbara, CNR, ISOF, I-40129 Bologna, Italy. (literal)

Titolo

• Switch On/Switch Off Signal in an MOF-Guest Crystalline Device (literal)

Abstract

• A metal organic framework (MOF) based on the [Cu(4)I(4)DABCO(2)] cluster (DABCO = 1,4-diazabicyclo[2.2.2]octane), MOF 1, shows bright emission with a maximum at 556 nm and an emission quantum yield of 0.53 in the solid state. When the large cavities of the MOF are loaded during the synthesis with different amounts of ferrocene {FeCp2, [((5)-C5H5)(2)Fe-II]}, the luminescence of MOF 1 decreases with the increase in the ferrocene content, reaching an almost complete quenching for 3.5 wt.-% of cage loading, corresponding to the complete filling of the MOF cavities. When an electric potential is applied to the FeCp2@MOF 1 deposited onto an ITO glass, the (FeCp2)-Cp-II is oxidised to (FeCp2+)-Cp-III, and the MOF 1 emission is partially switched on again, indicating that a photoinduced electron-transfer reaction is contributing to the quenching process. (literal)

Prodotto di

• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Autore CNR

• BARBARA VENTURA (Persona)
• ANDREA BARBIERI (Persona)

Insieme di parole chiave

• Keywords of "Switch On/Switch Off Signal in an MOF-Guest Crystalline Device" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR di

• BARBARA VENTURA (Persona)
• ANDREA BARBIERI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• European journal of inorganic chemistry (Rivista)

Insieme di parole chiave di

• Keywords of "Switch On/Switch Off Signal in an MOF-Guest Crystalline Device" (Insieme di parole chiave)