http://www.cnr.it/ontology/cnr/individuo/prodotto/ID265077
Mono- and Trinuclear Tripodal Platinum(II) Chelated Complexes Containing a Pyridine/Sulfoxide Based Anchoring Framework (Articolo in rivista)
- Type
- Label
- Mono- and Trinuclear Tripodal Platinum(II) Chelated Complexes Containing a Pyridine/Sulfoxide Based Anchoring Framework (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/ejic.201300042 (literal)
- Alternative label
Barattucci, Anna and Plutino, M. Rosaria and Faggi, Cristina and Bonaccorsi, Paola and Scolaro, Luigi Monsu and Aversa, Maria Chiara (2013)
Mono- and Trinuclear Tripodal Platinum(II) Chelated Complexes Containing a Pyridine/Sulfoxide Based Anchoring Framework
in European journal of inorganic chemistry (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Barattucci, Anna and Plutino, M. Rosaria and Faggi, Cristina and Bonaccorsi, Paola and Scolaro, Luigi Monsu and Aversa, Maria Chiara (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=AuthorFinder&qid=1&SID=Y2KCpB9aSP481UaRoDQ&page=1&doc=1 (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Univ Messina, Dipartimento Sci Chim, I-98166 Messina, Italy
CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati, c/o Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, V.le Ferdinando Stagno D'Alcontres 31, 98166 Vill. S. Agata, Messina, Italy
Univ Florence, Ctr Interdipartimentale Cristallog, I-50019 Florence, Italy (literal)
- Titolo
- Mono- and Trinuclear Tripodal Platinum(II) Chelated Complexes Containing a Pyridine/Sulfoxide Based Anchoring Framework (literal)
- Abstract
- New tripodal ligands 2,4,6-triethyl-1,3,5-tris{[1-(2-pyridinyl)ethenyl]sulfinylmethyl}ben zenes 6, characterized by three pendant chains each containing both sulfoxide and pyridine moieties, were synthesized from the corresponding sulfenic acid and 2-ethynylpyridine. Two diastereomeric mixtures were obtained and separated, one racemic mixture 6a, having a C3 symmetry axis and the other 6b with no symmetry. With the aim of studying the coordination ability of these chelating-N,S type ligands, monobranched racemic [1-(2-pyridinyl)ethenyl]sulfinylbenzene 9 was also synthesized. Upon addition of an equivalent amount of the monochelating ligand 9 or the tripodal species 6a to a CD3CN solution of a platinum(II) complex of the type cis-[PtMe2(Me2SO)2] (Pt1) or trans-[PtMeCl(Me2SO)2] (Pt2), platinum(II) coordination and chelation occurred, as definitively indicated by a sharp change in the 1H NMR spectrum towards the final corresponding chelated platinum(II) species and free dimethyl sulfoxide. The prepared platinum(II) species contain one or three fragments of the type {PtMe2}(10 or 12) and {PtMeCl}(11 or 13) bound to the pyridinyl/sulfinyl skeleton in the coordinating ligands 9 and 6a. All the prepared species were fully characterized by NMR spectroscopy from the connectivities in 2D-COSY, 1H-13C HSQC and phase-sensitive 2D-NOESY spectra which confirm the molecular mechanics calculation predictions. (literal)
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