A ferromagnetic mixed-valent Mn supertetrahedron: Towards low-temperature magnetic refrigeration with molecular clusters (Articolo in rivista)

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Label
  • A ferromagnetic mixed-valent Mn supertetrahedron: Towards low-temperature magnetic refrigeration with molecular clusters (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/anie.200701027 (literal)
Alternative label
  • Manoli, M; Johnstone, RDL; Parsons, S; Murrie, M; Affronte, M; Evangelisti, M; Brechin, EK (2007)
    A ferromagnetic mixed-valent Mn supertetrahedron: Towards low-temperature magnetic refrigeration with molecular clusters
    in Angewandte Chemie (Int. ed., Print); Wiley-VCH Verlag Gmbh, Weinheim (Germania)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Manoli, M; Johnstone, RDL; Parsons, S; Murrie, M; Affronte, M; Evangelisti, M; Brechin, EK (literal)
Pagina inizio
  • 4456 (literal)
Pagina fine
  • 4460 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 46 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, INFM, Natl Res Ctr NanoStruct & BioSyst Surfaces S3, I-41100 Modena, Italy; Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland; Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland (literal)
Titolo
  • A ferromagnetic mixed-valent Mn supertetrahedron: Towards low-temperature magnetic refrigeration with molecular clusters (literal)
Abstract
  • We report the synthesis and structure of the first example of a decametallic mixed-valent Mn supertetrahedron, using 2-amino-2-methyl-1,3-propanediol (ampdH2, Figure 1) that displays dominant ferromagnetic exchange and a spin ground state of S = 22. In addition, we show that the magnetic behaviour of the compound is particularly appealing in view of its possible application as an efficient low-temperature magnetic refrigerant. (literal)
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