http://www.cnr.it/ontology/cnr/individuo/prodotto/ID255831
An efficient enzymatic preparation of (+)- and (-)-conduritol E, a cyclitol with C2 symmetry (Articolo in rivista)
- Type
- Label
- An efficient enzymatic preparation of (+)- and (-)-conduritol E, a cyclitol with C2 symmetry (Articolo in rivista) (literal)
- Anno
- 1997-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/S0957-4166(97)00129-8 (literal)
- Alternative label
Claudia Sanfilippo, Angela Patti, Mario Piattelli, Giovanni Nicolosi (1997)
An efficient enzymatic preparation of (+)- and (-)-conduritol E, a cyclitol with C2 symmetry
in Tetrahedron: asymmetry (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Claudia Sanfilippo, Angela Patti, Mario Piattelli, Giovanni Nicolosi (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://dx.doi.org/10.1016/S0957-4166(97)00129-8 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto CNR Studio Sostanze Naturali di Interesse Alimentare e Chimico-Farmaceutico (literal)
- Titolo
- An efficient enzymatic preparation of (+)- and (-)-conduritol E, a cyclitol with C2 symmetry (literal)
- Abstract
- Lypozyme® IM (immobilised lipase from Mucor miehei) catalyses the enantiomeric alcoholysis of tetraacetylconduritol E (±)-2 to give enantiopure (1R,2R,3R,4R)-tetrahydroxycyclohex-5-ene, (-)-1, and the unreacted ester (1S,2S,3s,4S)-tetraacetyloxycyclohex-5-ene, (+)-2. The latter was transformed by basic hydrolysis into (+)-1 in high yield and 95% ee. Selective amination of partial ester (-)-3, obtained by short alcoholysis of (±)-2, furnished the previously unreported conduramine F-4, (-)-4. (literal)
- Prodotto di
- Autore CNR
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