Photoionization cross section and angular distribution calculations of carbon tetrafluoride (Articolo in rivista)

Type
Label
  • Photoionization cross section and angular distribution calculations of carbon tetrafluoride (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Alternative label
  • Toffoli, B; Stener, M; Fronzoni, G; Decleva, P (2006)
    Photoionization cross section and angular distribution calculations of carbon tetrafluoride
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Toffoli, B; Stener, M; Fronzoni, G; Decleva, P (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 124 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy; Natl Simulat Ctr, INFM DEMOCRITOS, I-34127 Trieste, Italy; Consorzio INSTM, Unita Trieste, I-34127 Trieste, Italy (literal)
Titolo
  • Photoionization cross section and angular distribution calculations of carbon tetrafluoride (literal)
Abstract
  • Correlation in the photoionization dynamics of carbon tetrafluoride is studied in the framework of the time-dependent density-functional. theory (TDDFT) approach by employing a multicentric basis set expansion of the scattering wave function linear combination of atomic orbitals (LCAO) TDDFT. Results obtained with the statistical average of orbital potentials and LB94 exchange-correlation (xc) potentials are compared with photoabsorption, photoionization, and electron-scattering experiments as Well as with past theoretical calculations. Inadequacies in both the V-xc parametrizations employed have been suggested from the analysis of the intensity plots for the (D) over tilde (2)A(1) ionization. The formation of resonant scattering states in selected continuum channels has been studied through the analysis of the dipole-prepared scattering wave function; our findings are then compared with results of electron-scattering calculations. Overall, the LCAO-TDDFT results highlight the effectiveness of the approach for the calculation of the unbound spectrum of fairly large molecules. (c) 2006 American Institute of Physics. (literal)
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