http://www.cnr.it/ontology/cnr/individuo/prodotto/ID253260
Synthesis and characterization of poly(ether ketone) poly(ether sulfone) alternating and sequential copolymers by electrophilic reactions (Articolo in rivista)
- Type
- Label
- Synthesis and characterization of poly(ether ketone) poly(ether sulfone) alternating and sequential copolymers by electrophilic reactions (Articolo in rivista) (literal)
- Anno
- 1996-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/macp.1996.021970320 (literal)
- Alternative label
Paolo Finocchiaro; Giorgio Montaudo; Patrizia Mertoli, Concetto Puglisi, Filippo Samperi (1996)
Synthesis and characterization of poly(ether ketone) poly(ether sulfone) alternating and sequential copolymers by electrophilic reactions
in Macromolecular chemistry and physics (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Paolo Finocchiaro; Giorgio Montaudo; Patrizia Mertoli, Concetto Puglisi, Filippo Samperi (literal)
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- Pagina fine
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- Rivista
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Università Catania; CNR (literal)
- Titolo
- Synthesis and characterization of poly(ether ketone) poly(ether sulfone) alternating and sequential copolymers by electrophilic reactions (literal)
- Abstract
- The synthesis aqd NMR characterization of some poly(ether ketone)/poly(ether sulfone)
(PEK/PES) alternating copolymers together with a series of sequential homopolymers
containing CO, 0, S and SO, bridging groups, all obtained by electrophilic condensation
reactions using phosphorus pentoxide/methanesulfonic acid as dehydrating agent, is here
reported. Properties of such polymers are compared with those of their model compounds
from which it can be inferred that both proton and carbon chemical shifts are very sensitive
to the electronic environment generated by the 0, S, CO and SO, bridges. Differential
scanning calorimetry indicates that our polymers are essentially amorphous irrespective of
the bridging sequence. From viscosity measurements the molecular weights of these
copolymers are judged to be very low. (literal)
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