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Second-Order Nonlinear Optical Properties of Tetradentate Schiff (Abstract in rivista)
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- Second-Order Nonlinear Optical Properties of Tetradentate Schiff (Abstract in rivista) (literal)
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- 2005-01-01T00:00:00+01:00 (literal)
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Forni A., Gradinaru J., Druta V., Tessore F., Zecchin S., Quici S., Gerbeleu N. (2005)
Second-Order Nonlinear Optical Properties of Tetradentate Schiff
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- Forni A., Gradinaru J., Druta V., Tessore F., Zecchin S., Quici S., Gerbeleu N. (literal)
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- IF 2005: 1.791;
SJR 2005: Structural Biology, Q2;
Abstract for a poster Presnentation at the XX IUCr Congress, Florence, Italy, 23-31 August 2005 (literal)
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- CNR-ISTM, Milan, Italy; Institute of Chemistry of the Academy of Sciences of Moldova, Chisinau, R. Moldova; Department of Inorganic Chemistry, Milan, Italy; CNR-IENI, Padua, Italy (literal)
- Titolo
- Second-Order Nonlinear Optical Properties of Tetradentate Schiff (literal)
- Abstract
- Quadratic non-linear optical properties of new unsymmetrical Ni(II), Cu(II), Zn(II) and VO(II) complexes with [N2O2] chelate tetradentate ligands are presented. The complexes were synthesized by template condensation of 1-phenylbutane-1,3-dione mono-Smethylisothiosemicarbazone with o-hydroxybenzaldehyde or its 5-phenylazo-derivative. The crystal structure of some complexes was determined by using synchrotron radiation (XRD1 beamline at ELETTRA, Trieste).
Large values of hyperpolarizability, as obtained for these complexes by the solution-phase dc electric-field-induced second harmonic (EFISH) generation method, together with their high stability constants, make them promising candidates for successful applications in the field of optoelectronic technologies.
The values of theoretical hyperpolarizability, calculated through both Finite Field and Time Dependent DFT methods, are also presented. (literal)
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