Enzymatic desymmetrisation of conduritol D. Preparation of homochiral intermediates for the synthesis of cyclitols and aminocyclitols (Articolo in rivista)

Type
Label
  • Enzymatic desymmetrisation of conduritol D. Preparation of homochiral intermediates for the synthesis of cyclitols and aminocyclitols (Articolo in rivista) (literal)
Anno
  • 1996-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/0957-4166(96)00342-4 (literal)
Alternative label
  • Angela Patti, Claudia Sanfilippo, Mario Piattelli, Giovanni Nicolosi (1996)
    Enzymatic desymmetrisation of conduritol D. Preparation of homochiral intermediates for the synthesis of cyclitols and aminocyclitols
    in Tetrahedron: asymmetry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Angela Patti, Claudia Sanfilippo, Mario Piattelli, Giovanni Nicolosi (literal)
Pagina inizio
  • 2665 (literal)
Pagina fine
  • 2670 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 7 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 9 (literal)
Note
  • Scopus (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto C.N.R. per lo Studio delle Sostanze Naturali di Interesse Alimentare e Chimico-Farmaceutico (literal)
Titolo
  • Enzymatic desymmetrisation of conduritol D. Preparation of homochiral intermediates for the synthesis of cyclitols and aminocyclitols (literal)
Abstract
  • From meso-conduritol D tetraacetate four homochiral partial derivatives, namely (+)-(1R,2R,3S,4S)-1-hydroxy-2,3,4-triacetoxy-5-cyclohexene, (-)-(1R,2R,3S,4S)-2-hydroxy-1,3,4-triacetoxy-5-cyclohexene, (-)-(1R,2R,3S,4S)-1-benzoyloxy-3,4-diacetoxy-2-hydroxy-5-cyclohexene and (+)-(1R,2R,3S,4S)-3,4-diacetoxy-1,2-dihydroxy-5-cyclohexene, have been prepared through enzymatic reactions catalysed by one of the following lipases: from porcine pancreas, from Mucor miehei and from Candida cylindracea. These compounds are of potential utility in the synthesis of cyclitols and aminocyclitols. As an example, the preparation of the previously unreported (+)-conduramine C-4 is also reported. (literal)
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