Hydrolysis at MgO(100)/Ag(100) oxide-metal interfaces studied by O 1s x-ray photoelectron and MgKL(23)L(23) Auger spectroscopy (Articolo in rivista)

Type
Label
  • Hydrolysis at MgO(100)/Ag(100) oxide-metal interfaces studied by O 1s x-ray photoelectron and MgKL(23)L(23) Auger spectroscopy (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1103/PhysRevB.76.205413 (literal)
Alternative label
  • Altieri, S; Contri, SF; Valeri, S (2007)
    Hydrolysis at MgO(100)/Ag(100) oxide-metal interfaces studied by O 1s x-ray photoelectron and MgKL(23)L(23) Auger spectroscopy
    in Physical review. B, Condensed matter and materials physics
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Altieri, S; Contri, SF; Valeri, S (literal)
Pagina inizio
  • 205413-1 (literal)
Pagina fine
  • 205413-7 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 76 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Natl Ctr Nanostruct & Biosyst Surface, CNR, INFM S3, I-41100 Modena, Italy; Univ Modena, Dipartimento Fis, I-41100 Modena, Italy (literal)
Titolo
  • Hydrolysis at MgO(100)/Ag(100) oxide-metal interfaces studied by O 1s x-ray photoelectron and MgKL(23)L(23) Auger spectroscopy (literal)
Abstract
  • Using O 1s x-ray photoelectron and Mg KL23L23 Auger spectroscopy, we demonstrate that monolayer MgO(100)/Ag(100) exposed at 300 K to H2O vapor pressure of 10(-8) Torr is strongly hydrated up to 0.8 H2O per MgO formula unit, half of the water molecules being dissociatively adsorbed at the fourfold coordinated surface oxide sites. These dramatic hydrolysis and molecular adsorption phenomena are strikingly different from those observed at perfect bulklike MgO(100) surfaces, and provide strong experimental support to the concept of unprecedented interactions and properties at oxide-metal interfaces. (literal)
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