Synthesis and Physical Characterization of Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Network (Articolo in rivista)

Type
Label
  • Synthesis and Physical Characterization of Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Network (Articolo in rivista) (literal)
Anno
  • 1999-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/pen.11445 (literal)
Alternative label
  • A. Bartolotta, G. Di Marco, G. Carini, G. D'Angelo, G. Tripodo, A. M. Fainleib, E. A. Slinchenko, V. I. Shtompel, V. P. Privalko. (1999)
    Synthesis and Physical Characterization of Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Network
    in Polymer engineering and science (Online)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • A. Bartolotta, G. Di Marco, G. Carini, G. D'Angelo, G. Tripodo, A. M. Fainleib, E. A. Slinchenko, V. I. Shtompel, V. P. Privalko. (literal)
Pagina inizio
  • 549 (literal)
Pagina fine
  • 558 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 39 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 3 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR IPCF UNIME Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine (literal)
Titolo
  • Synthesis and Physical Characterization of Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Network (literal)
Abstract
  • Semi-interpenetrating polymer networks (semi-IPN) of linear polyurethane (LPU) and heterocyclic polymer network (HPN) were characterized by IR spectroscopy, small-angle X-ray scattering, differential calorimetry with diathermal shells (temperature interval 130-500 K), and dynamic mechanical analysis (temperature interval 150-500 K and frequency range 0.3-30 Hz). The main results obtained may be summarized as follows: (1) The affinity of HPN towards the soft LPU microphase is responsible for the absence of large-scale heterogeneity of semi-IPNs on their base (at least, at low HPN/LPU ratios). (2) Phenomenological analysis of small-scale, Arrhenius-like subglass relaxations (?1 and ?2 in LPU and in HPN, respectively) revealed little interference of HPN with relaxation centers (RCs) of LPU in semi-IPNs, while the local environment of RCs in HPN, on the contrary, strongly depended on semi-IPN composition. (literal)
Prodotto di
Autore CNR

Incoming links:


Prodotto
Autore CNR di
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
data.CNR.it