http://www.cnr.it/ontology/cnr/individuo/prodotto/ID248869
Synthesis and Physical Characterization of Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Network (Articolo in rivista)
- Type
- Label
- Synthesis and Physical Characterization of Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Network (Articolo in rivista) (literal)
- Anno
- 1999-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/pen.11445 (literal)
- Alternative label
A. Bartolotta, G. Di Marco, G. Carini, G. D'Angelo, G. Tripodo, A. M. Fainleib, E. A. Slinchenko, V. I. Shtompel, V. P. Privalko. (1999)
Synthesis and Physical Characterization of Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Network
in Polymer engineering and science (Online)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- A. Bartolotta, G. Di Marco, G. Carini, G. D'Angelo, G. Tripodo, A. M. Fainleib, E. A. Slinchenko, V. I. Shtompel, V. P. Privalko. (literal)
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- CNR IPCF
UNIME
Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine (literal)
- Titolo
- Synthesis and Physical Characterization of Semi-IPNs of Linear Polyurethane and Heterocyclic Polymer Network (literal)
- Abstract
- Semi-interpenetrating polymer networks (semi-IPN) of linear polyurethane (LPU) and heterocyclic polymer network (HPN) were characterized by IR spectroscopy, small-angle X-ray scattering, differential calorimetry with diathermal shells (temperature interval 130-500 K), and dynamic mechanical analysis (temperature interval 150-500 K and frequency range 0.3-30 Hz). The main results obtained may be summarized as follows: (1) The affinity of HPN towards the soft LPU microphase is responsible for the absence of large-scale heterogeneity of semi-IPNs on their base (at least, at low HPN/LPU ratios). (2) Phenomenological analysis of small-scale, Arrhenius-like subglass relaxations (?1 and ?2 in LPU and in HPN, respectively) revealed little interference of HPN with relaxation centers (RCs) of LPU in semi-IPNs, while the local environment of RCs in HPN, on the contrary, strongly depended on semi-IPN composition. (literal)
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