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Dynamical behaviour of structured macromolecular solutions (Articolo in rivista)

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Label

Dynamical behaviour of structured macromolecular solutions (Articolo in rivista) (literal)

Anno

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Alternative label

F Farsaci, ME Fontanella, G Salvato, F Wanderlingh, R Giordano, U Wanderlingh (1989)
Dynamical behaviour of structured macromolecular solutions
in Physics and chemistry of liquids (Print); GORDON BREACH SCI PUBL LTD, C/O STBS LTD, PO BOX 90, READING, BERKS, ENGLAND RG1 8JL (Regno Unito)
(literal)

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F Farsaci, ME Fontanella, G Salvato, F Wanderlingh, R Giordano, U Wanderlingh (literal)

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Inst. of Spectroscopic Techniques, CNR, Messina, Italy Inst. of Physics-University, Messina, Italy (literal)

Titolo

Abstract

A large number of experimental results have shown that macromolelcules in solution give rise to ordered (thyxotropic) structures, a noticeable role being played by a dynamic correlation. In the present paper we develop a semi-phenomenological model that can be solved analytically. The model is able to describe in a quantitative way both structural and dynamical properties of a thyxotropic solution. A careful experimental investigation is also carried out and the experimental results are compared to the theoretical prediction. In such a way the relevant parameters implied in the structure can be evaluated. Some implications concerning energy exchanges between proteins and the thermal bath are discussed (literal)

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