Role of Interfacial Energy and Crystallographic Orientation on the Mechanism of the ZnO + Al2O3 -> ZnAl2O4 Solid-State Reaction: II. Reactivity of Films Deposited onto the Sapphire (001) Face (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Role of Interfacial Energy and Crystallographic Orientation on the Mechanism of the ZnO + Al2O3 -> ZnAl2O4 Solid-State Reaction: II. Reactivity of Films Deposited onto the Sapphire (001) Face (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/jp312517w (literal)

Alternative label

• Sonia Pin ab, Marco Suardelli b, Francesco D'Acapito c, Giorgio Spinolo b, Michele Zema d, Serena C. Tarantino d, Luisa Barba e, Paolo Ghigna b (2013)
  Role of Interfacial Energy and Crystallographic Orientation on the Mechanism of the ZnO + Al2O3 -> ZnAl2O4 Solid-State Reaction: II. Reactivity of Films Deposited onto the Sapphire (001) Face
  in Journal of physical chemistry. C; American Chemical Society, Washington (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Sonia Pin ab, Marco Suardelli b, Francesco D'Acapito c, Giorgio Spinolo b, Michele Zema d, Serena C. Tarantino d, Luisa Barba e, Paolo Ghigna b (literal)

Pagina inizio

• 6113 (literal)

Pagina fine

• 6119 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021%2Fjp312517w (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 117 (literal)

Rivista

• Journal of physical chemistry. C (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 12 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• a) General Energy Research (ENE), Laboratory for Bionenergy and Catalysis, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland b) INSTM, Department of Chemistry, University of Pavia, I27100 Pavia, Italy c) CNR-IOM-OGG c/o ESRF, GILDA-CRG, BP 220, F38043 Grenoble Cedex, France d) Department of Earth and Environment Sciences, University of Pavia, I27100 Pavia, Italy e) CNR - Institute of Crystallography, UOS Trieste, Strada Statale 14 - km 163,5 Area Science Park I34149 Basovizza, Trieste Italy (literal)

Titolo

• Role of Interfacial Energy and Crystallographic Orientation on the Mechanism of the ZnO + Al2O3 -> ZnAl2O4 Solid-State Reaction: II. Reactivity of Films Deposited onto the Sapphire (001) Face (literal)

Abstract

• The initial steps of the reaction between ZnO and (001)-oriented Al2O3 single crystals have been investigated with X-ray diffraction, atomic force microscopy, and X-ray absorption spectroscopy at the Zn?K edge starting from 45 nm thick zincite films. The reaction eventually yields the ZnAl2O4 spinel on this interface but via a complex mechanism involving side and intermediate nonequilibrium compounds, the spinel initially forming with a distribution of lattice parameters. Evidence is given of the fact that one of the side compounds has a crystal structure close to that of the Zn3In2O6 compound. The results are discussed in the general context of the same reaction on different single-crystal substrates and different film thicknesses. (literal)

Editore

• American Chemical Society (Editore)

Prodotto di

• Strumentazione cristallografica e applicazioni (PM.P06.002.003) (Modulo)
• Institute of Crystallography (IC) (Istituto)

Autore CNR

• FRANCESCO D'ACAPITO (Persona)
• LUISA BARBA (Persona)

Insieme di parole chiave

• Parole chiave di "Role of Interfacial Energy and Crystallographic Orientation on the Mechanism of the ZnO + Al2O3 -> ZnAl2O4 Solid-State Reaction: II. Reactivity of Films Deposited onto the Sapphire (001) Face" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• LUISA BARBA (Persona)
• FRANCESCO D'ACAPITO (Persona)

Prodotto

• Institute of Crystallography (IC) (Istituto)
• Strumentazione cristallografica e applicazioni (PM.P06.002.003) (Modulo)

Editore di

• American Chemical Society (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of physical chemistry. C (Rivista)

Insieme di parole chiave di

• Parole chiave di "Role of Interfacial Energy and Crystallographic Orientation on the Mechanism of the ZnO + Al2O3 -> ZnAl2O4 Solid-State Reaction: II. Reactivity of Films Deposited onto the Sapphire (001) Face" (Insieme di parole chiave)