Structural characterization of multicomponent copolyesters by mass spectrometry (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Structural characterization of multicomponent copolyesters by mass spectrometry (Articolo in rivista) (literal)

Anno

• 1998-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ma980821c (literal)

Alternative label

• Montaudo, MS Puglisi, C Samperi, F Montaudo, G (1998)
  Structural characterization of multicomponent copolyesters by mass spectrometry
  in Macromolecules (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Montaudo, MS Puglisi, C Samperi, F Montaudo, G (literal)

Pagina inizio

• 8666 (literal)

Pagina fine

• 8676 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 31 (literal)

Rivista

• Macromolecules (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 11 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 25 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• polimeri Catania (literal)

Titolo

• Structural characterization of multicomponent copolyesters by mass spectrometry (literal)

Abstract

• Abstract: The structural characterization and composition of five random copolyesters, originating from 1,4-butanediol and mixtures of succinic, adipic, sebacic, and terephthalic acids, were obtained by analysis of their fast atom bombardment (FAB) and their matrix-assisted laser desorption ionization (MALDI) mass spectra. Multicomponent condensation copolymers may sometimes prove difficult to characterize by conventional techniques, whereas mass spectrometry is able to handle them. Once the choice between Bernoullian or Markoffian models has been made, the determination of copolymer composition, number-average sequence length, and related quantities can be achieved by applying well-defined analytical equations. The theoretical mass spectra of multicomponent copolymers are remarkably simple, and the number of peaks appearing in each copolymer mass spectrum is easily predictable. Different kinds of spectral fitting algorithms may help in the actual computations, and it has been shown that the apparent complexity of mass spectra of copolymers is due to the presence of mass series bearing different end groups. By selecting a single mass series, one obtains an experimental spectrum immediately comparable to the theoretical one. Detailed examples, together with a discussion on the reliability of results, are given to apply the computation procedures and to gain proper understanding of the concepts involved. (literal)

Prodotto di

• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)

Autore CNR

• FILIPPO SAMPERI (Persona)
• MAURIZIO MONTAUDO (Unità di personale interno)
• CONCETTO PUGLISI (Unità di personale interno)

Incoming links:

Autore CNR di

• FILIPPO SAMPERI (Persona)
• CONCETTO PUGLISI (Unità di personale interno)
• MAURIZIO MONTAUDO (Unità di personale interno)

Prodotto

• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Macromolecules (Rivista)