Characterization of end groups in nylon 6 by MALDI-TOF mass spectrometry (Articolo in rivista)

Type
Label
  • Characterization of end groups in nylon 6 by MALDI-TOF mass spectrometry (Articolo in rivista) (literal)
Anno
  • 1996-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/(SICI)1099-0518(199602)34:3<439::AID-POLA13>3.0.CO;2-Q (literal)
Alternative label
  • MONTAUDO G, MONTAUDO MS, PUGLISI C, SAMPERI F, (1996)
    Characterization of end groups in nylon 6 by MALDI-TOF mass spectrometry
    in Journal of polymer science. Part A, Polymer chemistry
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • MONTAUDO G, MONTAUDO MS, PUGLISI C, SAMPERI F, (literal)
Pagina inizio
  • 439 (literal)
Pagina fine
  • 447 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1099-0518(199602)34:3%3C439::AID-POLA13%3E3.0.CO;2-Q/abstract (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 34 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 8 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 3 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • polimeri (literal)
Titolo
  • Characterization of end groups in nylon 6 by MALDI-TOF mass spectrometry (literal)
Abstract
  • Abstract: Four samples of Ny6, each terminated by different end groups, i.e., diamino terminated, monoamino terminated (monocapped), dicarboxyl terminated, and amino-carboxyl terminated, were synthesized and analyzed by MALDI-TOF Mass Spectrometry, in order to accurately characterize their structure by direct identification of mass resolved chains. A self-calibrating method for the MALDI-TOF mass spectra of polymeric samples was used in order to distinguish the end groups existing in the four samples of Ny6. The MALDI-TOF spectra showed the presence of protonated, sodiated, and potassiated ions that were assigned to Ny6 chains containing the expecteted end groups. Furthermore, the MALDI-TOF spectra made possible the simultaneous detection of the cyclic oligomers of Ny6 present in these samples, thus achieving the full structural characterization of the molecular species present in these polyamides. (literal)
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