HEMIPORPHYRAZINE, A PORPHYRIN-RELATED MACROCYCLE THAT INDUCES RHOMBICALLY COMPRESSED STEREOCHEMISTRIES - STRUCTURE AND PROPERTIES OF BIS(PYRIDINE)(HEMIPORPHYRAZINATO)NICKEL(II) (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• HEMIPORPHYRAZINE, A PORPHYRIN-RELATED MACROCYCLE THAT INDUCES RHOMBICALLY COMPRESSED STEREOCHEMISTRIES - STRUCTURE AND PROPERTIES OF BIS(PYRIDINE)(HEMIPORPHYRAZINATO)NICKEL(II) (Articolo in rivista) (literal)

Anno

• 1984-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ic00176a029 (literal)

Alternative label

• AGOSTINELLI, E; ATTANASIO, D; COLLAMATI, I; FARES, V (1984)
  HEMIPORPHYRAZINE, A PORPHYRIN-RELATED MACROCYCLE THAT INDUCES RHOMBICALLY COMPRESSED STEREOCHEMISTRIES - STRUCTURE AND PROPERTIES OF BIS(PYRIDINE)(HEMIPORPHYRAZINATO)NICKEL(II)
  in Inorganic chemistry; ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• AGOSTINELLI, E; ATTANASIO, D; COLLAMATI, I; FARES, V (literal)

Pagina inizio

• 1162 (literal)

Pagina fine

• 1165 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://biblioproxy.cnr.it:2054/doi/abs/10.1021/ic00176a029?journalCode=inocaj&quickLinkVolume=23&quickLinkPage=1162&selectedTab=citation&volume=23 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 23 (literal)

Rivista

• Inorganic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 4 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 8 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Teoria e Struttura Elettronica e Comportamento Spettrochimico dei Composti di Coordinazione del CNR, 00016 Monterotondo Stazione, Rome, Italy (literal)

Titolo

• HEMIPORPHYRAZINE, A PORPHYRIN-RELATED MACROCYCLE THAT INDUCES RHOMBICALLY COMPRESSED STEREOCHEMISTRIES - STRUCTURE AND PROPERTIES OF BIS(PYRIDINE)(HEMIPORPHYRAZINATO)NICKEL(II) (literal)

Abstract

• The title compound crystallizes in the P2,/c space group with Z = 4, a = 16.418 (7) A, b = 9.727 (4) A, c = 18.632 (6) A, and /3 = 94.59 (3)'. The stereochemistry is rhombically compressed with the unique axis defined by the metal isoindole nitrogen atoms, which are 1.97 A from the nickel ion. The other two Ni-N distances are 2.18 and 2.22 A, for the macrocyclic and adduct pyridine nitrogen atoms, respectively. In agreement with this, the EPR spectrum of the Cu-doped nickel complex is typical of a predominant Iz2) ground state with a strong rhombic component. %her related complexes were investigated by EPR spectroscopy and found to have a qualitatively similar geometry due to the \"elliptical\" coordination hole of the hemiporphyrazinato ligand. (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• Institute of structure of matter (ISM) (Istituto)

Autore CNR

• VINCENZO FARES (Persona)
• ELISABETTA AGOSTINELLI (Persona)
• DONATO ATTANASIO (Unità di personale esterno)

Insieme di parole chiave

• Parole chiave di "HEMIPORPHYRAZINE, A PORPHYRIN-RELATED MACROCYCLE THAT INDUCES RHOMBICALLY COMPRESSED STEREOCHEMISTRIES - STRUCTURE AND PROPERTIES OF BIS(PYRIDINE)(HEMIPORPHYRAZINATO)NICKEL(II)" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of structure of matter (ISM) (Istituto)

Autore CNR di

• ELISABETTA AGOSTINELLI (Persona)
• VINCENZO FARES (Persona)
• DONATO ATTANASIO (Unità di personale esterno)

Editore di

• ACS, American chemical society (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "HEMIPORPHYRAZINE, A PORPHYRIN-RELATED MACROCYCLE THAT INDUCES RHOMBICALLY COMPRESSED STEREOCHEMISTRIES - STRUCTURE AND PROPERTIES OF BIS(PYRIDINE)(HEMIPORPHYRAZINATO)NICKEL(II)" (Insieme di parole chiave)