Optical spectroscopy of Eu3+ ion as a tool for the study of dehydration process in silica gels (Articolo in rivista)

Type
Label
  • Optical spectroscopy of Eu3+ ion as a tool for the study of dehydration process in silica gels (Articolo in rivista) (literal)
Anno
  • 1994-01-01T00:00:00+01:00 (literal)
Alternative label
  • Piazza, A.1 , Bouajaj, A. 1, Ferrari, M. 1, Montagna, M. 2, Campostrini, R. 3, Carturan, G. 3 (1994)
    Optical spectroscopy of Eu3+ ion as a tool for the study of dehydration process in silica gels
    in Journal de physique. IV
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Piazza, A.1 , Bouajaj, A. 1, Ferrari, M. 1, Montagna, M. 2, Campostrini, R. 3, Carturan, G. 3 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 4 (literal)
Rivista
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  • 1CNR,Centro di Fisica degli Stati Aggregati ed Impianto fonico, via Sommarive 14, 38050 Povo (TN),Italy 2Dipartimento di Fisica, Universita di Trento, via Sommarive 14, 38050 Povo (TN),Italy 3Dipartimento di Ingegneria dei Materiali,Università di Trento, 38050 Mesiano (TN),Italy (literal)
Titolo
  • Optical spectroscopy of Eu3+ ion as a tool for the study of dehydration process in silica gels (literal)
Abstract
  • The structural modification induced by dehydration in optical silica gel has been studied using the spectroscopy of Eu3+ ion. The samples, doped with molar ratio Eu/Si = 0.01:1, were heated for 48 hours at different temperatures from 60 °C to 200 °C. Information on the dinamical properties of the local environment of the Eu3+ were obtained both by fluorescence and excitation measurements at T=11 K. The analysis of the 5D0 -> 7F0 transition appears of particular relevance in this study, because the transition is between J=0 states and does not present internal structure. Its inhomogeneous linewidth gives a measure of the energy distribution of the different Eu3+ sites. Site selection spectroscopy was performed by exciting into the 5D1 state. Three different sets of sites were found. The phonon sidebands of the 5D0 <- F0 and 5D1 <- 7F0 transitions were observed in the excitation spectra. (literal)
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